Department of Marine, Earth, and Atmospheric Sciences, 5135 Jordan Hall, North Carolina State University, Raleigh, North Carolina, USA.
Department of Civil, Construction, and Environmental Engineering, North Carolina State University, Raleigh, North Carolina, USA.
Water Environ Res. 2024 Aug;96(8):e11091. doi: 10.1002/wer.11091.
Perfluoroalkyl and polyfluoroalkyl substances (PFAS) are widespread groundwater contaminants and are present in over 7000 drinking water wells near a North Carolina (NC) PFAS plant (Chemours). To understand options available to affected residents, we used new and previously existing water quality data to investigate deeper aquifers as alternate drinking water supplies and compared the regulatory responses near Chemours and three other PFAS production facilities with nearby contaminated wells. Data from >100 wells show that GenX concentrations decrease with increasing depth through the four aquifers in the study area: surficial, Black Creek, Upper Cape Fear, and bedrock. This illustrates the extent of vertical PFAS penetration through the aquifer sequence following roughly 40 years of atmospheric emissions. Detailed data on 143 water quality parameters in nine deep wells (two Upper Cape Fear, seven bedrock) revealed only eight exceedances of drinking water standards (one each for arsenic, perfluorooctanoic acid [PFOA], iron, chloride, and gross alpha, and three for manganese) and nine exceedances of health advisories (all for sodium). Regulatory responses to PFAS contamination of wells in four states included mention of deeper wells as an alternate water source only for nonresidential users in NC and residential users in Vermont. The bedrock aquifer is currently used by some residents and may be a viable alternative to shallower groundwater, though arsenic treatment may be beneficial at some deep wells and long-term sustainability of the aquifer should be evaluated. PRACTITIONER POINTS: GenX concentrations decreased with increasing depth in four aquifers near a PFAS plant. A few exceedances of drinking water standards and health advisories were found in deep bedrock wells. New bedrock wells could be part of the response to PFAS issues in shallower wells. In the long term, deep bedrock wells might be a less expensive option for some residents.
全氟烷基和多氟烷基物质(PFAS)是广泛存在的地下水污染物,在北卡罗来纳州(NC)一家 PFAS 工厂(科慕)附近的 7000 多个饮用水井中都有发现。为了了解受影响居民的可用选择,我们使用新的和以前存在的水质数据来研究更深的含水层作为替代饮用水供应,并将 Chemours 附近以及其他三个 PFAS 生产设施附近受污染水井的监管反应进行了比较。来自 >100 口井的数据表明,在研究区域的四个含水层中,随着深度的增加,GenX 浓度逐渐降低:表层、黑溪、上卡弗尔和基岩。这说明了在大约 40 年的大气排放之后,PFAS 通过含水层序列垂直渗透的程度。在九口深井(两口上卡弗尔井,七口基岩井)中对 143 个水质参数的详细数据显示,只有八项超过饮用水标准(一项为砷、全氟辛酸 [PFOA]、铁、氯和总α,三项为锰)和九项超过健康建议(均为钠)。四个州对水井中 PFAS 污染的监管反应仅包括提及在 NC 为非住宅用户和佛蒙特州的住宅用户提供更深的水井作为替代水源。基岩含水层目前被一些居民使用,可能是浅层地下水的可行替代品,尽管一些深井可能需要进行砷处理,并且应该评估含水层的长期可持续性。从业者要点:在 PFAS 工厂附近的四个含水层中,GenX 浓度随着深度的增加而降低。在一些深井的基岩中发现了几项饮用水标准和健康建议的超标。新的基岩井可能是应对浅层井中 PFAS 问题的一部分。从长远来看,对于一些居民来说,深基岩井可能是一种更经济的选择。