Department of Petroleum Engineering, Faculty of Engineering, Soran University, Soran, Kurdistan Region, Iraq.
Department of Geology, Palacký University, 17. Listopadu 12, Olomouc, 77146, Czech Republic.
Environ Sci Pollut Res Int. 2024 Aug;31(39):51381-51400. doi: 10.1007/s11356-024-34561-7. Epub 2024 Aug 7.
Addressing the increasing demand for green additives in drilling fluids is essential for the sustainable development of the oil and gas industry. Fluid loss into porous and permeable formations during drilling presents significant challenges. This study introduced an innovative, environmentally sustainable drilling fluid known as nano-biodegradable drilling fluid (NBDF). The NBDF formulation incorporates greenly synthesized zinc nanorods (ZNRs) and gundelia seed shell powder, with ZNRs derived from Cydonia oblonga plant extracts using an eco-friendly method. The research developed multiple drilling fluid variants for experimentation: a reference drilling fluid (BM); biodegradable drilling fluid (BDF) with particle sizes of 75, 150, 300, and 600 µm at concentrations ranging from 0.5 to 1 wt% (GSMs); a drilling nanofluid (DNF) with ZNRs at a 0.1 wt% concentration (ZNR); and NBDF combining both nano and gundelia waste (GS-ZNR). Experimental tests were conducted under various temperature and pressure conditions, including low temperature and low pressure (LTLP) and high temperature and high pressure (HTHP). Rheological and filtration measurements were performed to assess the impact of the nano-biodegradable additives on flow behavior and fluid loss. Results indicated that incorporating 1 wt% of gundelia seed shell powder with a particle size of 75 µm led to a 19.61% reduction in fluid loss compared to BM at 75 °C and 200 psi. The performance of the same GSM improved by 31% under identical conditions when 1 wt% of zinc ZNRs was added. Notably, the GS-ZNR formulation demonstrated the most effective performance in reducing fluid loss into the formation, decreasing mud cake thickness, and enhancing the flow behavior of the non-Newtonian reference drilling fluid. This study highlights the relevance of particle size in the effectiveness of biodegradable additives and underscores the potential of NBDF to address environmental concerns in the oil and gas drilling industry.
解决钻井液中绿色添加剂需求不断增加的问题,对于石油和天然气行业的可持续发展至关重要。在钻井过程中,钻井液会滤失到多孔和渗透性地层中,这带来了巨大的挑战。本研究引入了一种创新性的、环境可持续的钻井液,即纳米可生物降解钻井液(NBDF)。NBDF 配方中包含了绿色合成的氧化锌纳米棒(ZNRs)和荆芥籽壳粉,其中 ZNRs 是由榅桲植物提取物通过环保方法制备的。研究团队开发了多种钻井液变体进行实验:基准钻井液(BM);生物降解钻井液(BDF),粒径为 75、150、300 和 600 µm,浓度范围为 0.5 至 1wt%(GSMs);纳米钻井液(DNF),ZNRs 浓度为 0.1wt%(ZNR);以及同时包含纳米和荆芥废弃物的 NBDF(GS-ZNR)。实验测试在各种温度和压力条件下进行,包括低温低压(LTLP)和高温高压(HTHP)。流变和过滤测量用于评估纳米可生物降解添加剂对流动行为和滤失量的影响。结果表明,在 75°C 和 200 psi 下,与 BM 相比,添加 1wt%粒径为 75 µm 的荆芥籽壳粉可将滤失量降低 19.61%。在相同条件下,添加 1wt%锌 ZNRs 时,相同 GSM 的性能提高了 31%。值得注意的是,GS-ZNR 配方在减少滤失量进入地层、降低泥饼厚度和增强非牛顿基准钻井液的流动行为方面表现出最有效的性能。本研究强调了粒径在可生物降解添加剂有效性中的重要性,并突出了 NBDF 在解决石油和天然气钻井行业环境问题方面的潜力。