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亚洲和欧洲各国河流沉积物中重金属污染研究综述:分布、来源及环境风险。

A review of heavy metals pollution in riverine sediment from various Asian and European countries: Distribution, sources, and environmental risk.

机构信息

Department of Environmental and Conservation Sciences, University of Swat, Swat 19120, Pakistan.

Department of Environmental and Conservation Sciences, University of Swat, Swat 19120, Pakistan; State Key Laboratory of Urban and Regional Ecology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China.

出版信息

Mar Pollut Bull. 2024 Sep;206:116775. doi: 10.1016/j.marpolbul.2024.116775. Epub 2024 Aug 8.

Abstract

Riverine sediments are important reservoirs of heavy metals, representing both historical and contemporary anthropogenic activity within the watershed. This review has been conducted to examine the distribution of heavy metals in the surface sediment of 52 riverine systems from various Asian and European countries, as well as to determine their sources and environmental risks. The results revealed significant variability in heavy metal contamination in the world's riverine systems, with certain hotspots exhibiting concentrations that exceeded the permissible limits set by environmental quality standards. Among the studied countries, India has the highest levels of chromium (Cr), cobalt (Co), manganese (Mn), nickel (Ni), zinc (Zn), cadmium (Cd), copper (Cu), and lead (Pb) contamination in its riverine systems, followed by Iran > Turkey > Spain > Vietnam > Pakistan > Malaysia > Taiwan > China > Nigeria > Bangladesh > Japan. Heavy metal pollution in the world's riverine systems was quantified using pollution evaluation indices. The Contamination Factor (CF) revealed moderate contamination (1 ≤ CF < 3) throughout the geological units, with the exception of Pb, Cd, and Cu. The Contamination Degree (CD) classifies the contamination level into different categories: Low degree of contamination (CD < 6), moderate degree of contamination (6 ≤ CD < 12), considerable degree of contamination (12 ≤ CD < 24), and a very high degree of contamination (CD ≥ 24), while the Pollution Load Index (PLI) estimate the total amount of heavy metal pollution in riverine sediments, with Turkey having the highest PLI value of 6.512, followed by Spain, Vietnam, Taiwan, Pakistan, Bangladesh, China, India, Japan, Malaysia, Iran, and Nigeria. In applied multivariate statistics, correlation analysis determined the fate and distribution of heavy metals in riverine systems, while Principal Component Analysis (PCA) elucidated the potential sources, including industrial, agrochemical, mining, and domestic wastewater discharges, lubricant leakages, multiple geogenic inputs, erosion of mafic and ultramafic rocks, and minimal atmospheric deposition. As per Potential Ecological Risk Index (PERI) perspectives, Vietnam, Spain, and Turkey have the highest ecological risk, followed by Nigeria > Pakistan > Bangladesh > China > Taiwan > Japan and Iron, while the potential risks of ∑non-carcinogenic Pb, Cr, Ni, Cu, Cd, Co, Zn, and Mn for exposed human children and adults through ingestion and dermal contact were significantly influenced between acceptable to high risk, necessitating special attention from pollution control agencies.

摘要

河流沉积物是重金属的重要储存库,代表了流域内历史和当代人为活动的双重影响。本综述旨在研究亚洲和欧洲各国 52 个河流水系表层沉积物中重金属的分布情况,并确定其来源和环境风险。结果表明,世界范围内河流水系的重金属污染存在显著差异,某些热点地区的浓度超过了环境质量标准规定的允许限值。在所研究的国家中,印度的河流水系中铬 (Cr)、钴 (Co)、锰 (Mn)、镍 (Ni)、锌 (Zn)、镉 (Cd)、铜 (Cu) 和铅 (Pb) 的污染水平最高,其次是伊朗>土耳其>西班牙>越南>巴基斯坦>马来西亚>中国台湾>中国>尼日利亚>孟加拉国>日本。使用污染评估指数对世界河流水系中的重金属污染进行了量化。污染因子 (CF) 表明除 Pb、Cd 和 Cu 外,地质单元中存在中等程度的污染 (1 ≤ CF < 3)。污染程度 (CD) 将污染水平分为不同类别:低污染程度 (CD < 6)、中等污染程度 (6 ≤ CD < 12)、相当污染程度 (12 ≤ CD < 24) 和极高污染程度 (CD ≥ 24),而污染负荷指数 (PLI) 则估算了河流水系中重金属污染的总量,土耳其的 PLI 值最高,为 6.512,其次是西班牙、越南、中国台湾、巴基斯坦、孟加拉国、中国、印度、日本、马来西亚、伊朗和尼日利亚。在应用多元统计中,相关分析确定了重金属在河流水系中的归宿和分布,而主成分分析 (PCA) 则阐明了潜在的污染源,包括工业、农用化学品、矿业和生活污水排放、润滑剂泄漏、多种地球化学输入、基性和超基性岩石的侵蚀以及最小的大气沉积。根据潜在生态风险指数 (PERI) 的观点,越南、西班牙和土耳其的生态风险最高,其次是尼日利亚>巴基斯坦>孟加拉国>中国>中国台湾>日本和铁,而∑非致癌性 Pb、Cr、Ni、Cu、Cd、Co、Zn 和 Mn 对暴露于人类儿童和成人的经口摄入和皮肤接触的潜在风险则从可接受至高风险显著影响,需要污染控制机构的特别关注。

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