Chen Ying, Li Xiang, Zhang Zherui, Liu Jiating, Lu Jiawei, Chen Yi
College of Civil Engineering, Hunan University of Technology, Zhuzhou, Hunan 412007, China.
Hunan Provincial Key Laboratory of Biomass Fiber Functional Materials, School of Packaging Materials and Engineering, Hunan University of Technology, Zhuzhou, Hunan 412007, China.
J Phys Chem B. 2024 Sep 5;128(35):8592-8604. doi: 10.1021/acs.jpcb.4c03008. Epub 2024 Aug 22.
Flexible piezoresistive sensors, which can convert specific mechanical information (such as compression, bending, tensile, and torsion) into a resistance value change signal through the piezoresistive effect, have attracted more and more attention. However, how to achieve the simple, low-cost fabrication of a piezoresistive sensor is still a challenge. Herein, we report a facile strategy that introduces conductive carbon black (CB) and shear thickening gel (SG) composite into a melamine sponge (MS) to generate an MS-SG-CB composite with a unique force-electric coupling effect. A flexible sensor derived from the MS-SG-CB composite can not only accurately identify deformation signals during static stretching and compression while monitoring human movement status in real time but also recognize electrical signals under dynamic impact in a very short time (6 ms). The 3 × 3 flexible array built on this basis can accurately identify the mass and position of heavy objects. Furthermore, based on the flame-retardant properties of MS, the flame-retardant ammonium polyphosphate (APP) is further introduced into MS-SG-CB to obtain MS-SG-CB-APP composite with excellent flame retardancy and stable temperature electrical response behavior, expanding its application in the field of high temperature trigger alarm.
柔性压阻式传感器能够通过压阻效应将特定的机械信息(如压缩、弯曲、拉伸和扭转)转换为电阻值变化信号,因而受到越来越多的关注。然而,如何实现压阻式传感器的简单、低成本制造仍是一项挑战。在此,我们报道了一种简便策略,即将导电炭黑(CB)和剪切增稠凝胶(SG)复合材料引入三聚氰胺海绵(MS)中,以生成具有独特力电耦合效应的MS-SG-CB复合材料。由MS-SG-CB复合材料制成的柔性传感器不仅能够在静态拉伸和压缩过程中准确识别变形信号,同时实时监测人体运动状态,还能在极短时间(6毫秒)内识别动态冲击下的电信号。在此基础上构建的3×3柔性阵列能够准确识别重物的质量和位置。此外,基于MS的阻燃性能,进一步将阻燃剂聚磷酸铵(APP)引入MS-SG-CB中,得到具有优异阻燃性和稳定温度电响应行为的MS-SG-CB-APP复合材料,拓展了其在高温触发报警领域的应用。