Li Yao, Zhao PengCheng, Shen Boxiong
School of Chemical Engineering & Technology, Hebei University of Technology, China.
Tianjin Key Laboratory of Clean Energy and Pollution Control, Hebei Engineering Research Center of Pollution Control in Power System, School of Energy and Environmental Engineering, Hebei University of Technology, Tianjin 300131, China.
Sci Total Environ. 2024 Nov 15;951:175459. doi: 10.1016/j.scitotenv.2024.175459. Epub 2024 Aug 20.
Lithium-ion batteries (LIBs) are widely used in various aspects of human life and production due to their safety, convenience, and low cost, especially in the field of electric vehicles (EVs). Currently, the number of LIBs worldwide is growing exponentially, which also leads to an increase in discarded LIBs. Spent lithium-ion batteries (S-LIBs) contain valuable metals and environmentally hazardous chemicals, necessitating proper resource recovery and harmless treatment of these S-LIBs. Therefore, research on S-LIBs recycling is beneficial for sustainable EVs development. This paper aims to critically review the research progress in the field of S-LIBs recycling, focusing on the recycling technology of cathode materials. First, the article introduces the composition, classification, and working principle of LIB. It then discusses the evaluation and monitoring of batteries that can no longer be used, so that they can be repurposed or dismantled for disposal. Subsequently, introduces that batteries that can no longer be used should undergo evaluation and monitoring for repurposing or dismantling. Emphasize the treatment of cathode materials, including two traditional recycling methods hydrometallurgy and pyrometallurgy as well as five new direct regeneration technologies and the application of cathode materials in non-battery fields. This work is expected to systematically demonstrate the treatment of S-LIBs and is of great significance for the sustainable EVs development of the LIB industry.
锂离子电池(LIBs)因其安全性、便利性和低成本而广泛应用于人类生活和生产的各个方面,尤其是在电动汽车(EVs)领域。目前,全球锂离子电池的数量呈指数级增长,这也导致了废旧锂离子电池数量的增加。废旧锂离子电池(S-LIBs)含有有价值的金属和对环境有害的化学物质,因此需要对这些废旧锂离子电池进行适当的资源回收和无害化处理。因此,对废旧锂离子电池回收的研究有利于电动汽车的可持续发展。本文旨在对废旧锂离子电池回收领域的研究进展进行批判性综述,重点关注正极材料的回收技术。首先,文章介绍了锂离子电池的组成、分类和工作原理。然后讨论了对无法再使用的电池进行评估和监测,以便对其进行重新利用或拆解处置。随后介绍了对无法再使用的电池应进行评估和监测以便重新利用或拆解。强调了正极材料的处理,包括两种传统回收方法——湿法冶金和火法冶金,以及五种新的直接再生技术和正极材料在非电池领域的应用。这项工作有望系统地展示废旧锂离子电池的处理方法,对锂离子电池行业电动汽车的可持续发展具有重要意义。