Zhou Jinxi, Zhang Junling, Jiang Guoxian, Xie Kai
School of Intelligent Manufacturing, Weifang University of Science and Technology, Weifang 262700, China.
ACS Omega. 2024 Aug 12;9(33):35929-35936. doi: 10.1021/acsomega.4c05145. eCollection 2024 Aug 20.
Ocean-going ships powered by diesel engines were the main source of CO emissions in the marine environment, and it was imperative to study shipboard carbon capture technology. Based on this, the whole process of CO absorption and desorption was studied with a mixed amine (MEA + AMP). The effective cycle time, CO absorption capacity, desorption efficiency, energy consumption, foaming and volatilization characteristics, and other key parameters were compared and analyzed under the conditions of required capture efficiency by ships. The MEA20% + AMP10% solution showed good CO absorption performance. At 80% capture efficiency, the desorption efficiency was more than 50%. The absorption capacity was close to that of the MEA30% solution, and the cycle time was basically the same. The effective cycle time under the reaction time of 2 s was also determined, which was an important parameter for setting the desorption frequency and had a great effect on reducing the desorption energy consumption. This work can provide an important reference value for the real ship application of carbon capture devices.
以柴油发动机为动力的远洋船舶是海洋环境中一氧化碳排放的主要来源,因此研究船上碳捕获技术势在必行。基于此,采用混合胺(MEA + AMP)对一氧化碳吸收和解吸的全过程进行了研究。在船舶所需捕获效率的条件下,对有效循环时间、一氧化碳吸收能力、解吸效率、能耗、发泡和挥发特性等关键参数进行了比较和分析。MEA20% + AMP10%溶液表现出良好的一氧化碳吸收性能。在捕获效率为80%时,解吸效率超过50%。吸收能力接近MEA30%溶液,循环时间基本相同。还确定了反应时间为2 s时的有效循环时间,这是设定解吸频率的重要参数,对降低解吸能耗有很大影响。这项工作可为碳捕获装置在实船应用中提供重要的参考价值。