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通过不可约表示和磁空间群分析研究非中心对称磁体SrMnSiO的磁结构

Magnetic structure of the noncentrosymmetric magnet SrMnSiO through irreducible representation and magnetic space group analyses.

作者信息

Nambu Y, Kawamata M, Pang X, Murakawa H, Avdeev M, Kimura H, Masuda H, Hanasaki N, Onose Y

机构信息

Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan.

Department of Physics, Tohoku University, Sendai 980-8578, Japan.

出版信息

Acta Crystallogr B Struct Sci Cryst Eng Mater. 2024 Oct 1;80(Pt 5):393-400. doi: 10.1107/S2052520624007625. Epub 2024 Sep 11.

Abstract

Magnetic structures of the noncentrosymmetric magnet SrMnSiO were examined through neutron diffraction for powder and single-crystalline samples, as well as magnetometry measurements. All allowed magnetic structures for space group P42m with the magnetic wavevector q = (0, 0, ½) were refined via irreducible representation and magnetic space group analyses. The compound was refined to have in-plane magnetic moments within the magnetic space group Cmc2.1' (No. 36.177) under zero field, which can be altered to P222.1' (No. 19.28) above μH = 0.067 (5) T to align induced weak-ferromagnetic components within one layer on the ab plane. All refined parameters are provided following the recent framework based upon the magnetic space group, which better conveys when exchanging crystallographic information for commensurate magnetic structures.

摘要

通过对粉末和单晶样品进行中子衍射以及磁测量,研究了非中心对称磁体SrMnSiO的磁结构。通过不可约表示和磁空间群分析,对具有磁波矢q = (0, 0, ½)的空间群P42m的所有允许磁结构进行了精修。该化合物在零场下在磁空间群Cmc2.1'(编号36.177)中被精修为具有面内磁矩,在μH = 0.067 (5) T以上可转变为P222.1'(编号19.28),以使ab平面上一层内的感应弱铁磁分量对齐。所有精修参数均按照基于磁空间群的最新框架给出,这在交换相称磁结构的晶体学信息时能更好地传达相关信息。

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