Zhang Xinyue, Yang Qiaoling, Gu Shuqing, Yu Yongai, Deng Xiaojun, Niu Bing, Chen Qin
School of Life Sciences, Shanghai University, Shanghai 200444, China.
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China.
J Dairy Sci. 2025 Jan;108(1):136-151. doi: 10.3168/jds.2024-25309. Epub 2024 Sep 28.
This study developed an efficient method for identifying and quantitatively analyzing animal-origin milk powders using Raman spectroscopy combined with chemometrics. By employing the MultiClassClassifier model, the method achieved high accuracy in distinguishing various types of animal-origin milk powders, with sensitivity and specificity both exceeding 80% and an overall accuracy of 93%. Furthermore, the quantitative models based on partial least squares regression and support vector machine regression exhibited excellent linear correlations, with both root mean square error and mean relative error below 0.2. These models successfully quantified adulteration in camel, mare, and donkey milk powders in comparison to goat and cow milk powders. The study's approach not only holds significant promise for detecting adulteration in specialty milk powders but also demonstrates wide applicability in analyzing other powdered adulterants.
本研究开发了一种利用拉曼光谱结合化学计量学来鉴定和定量分析动物源性奶粉的有效方法。通过采用多类分类器模型,该方法在区分各类动物源性奶粉方面取得了高精度,灵敏度和特异性均超过80%,总体准确率达93%。此外,基于偏最小二乘回归和支持向量机回归的定量模型表现出优异的线性相关性,均方根误差和平均相对误差均低于0.2。与山羊奶粉和牛奶粉相比,这些模型成功地对骆驼奶粉、马奶粉和驴奶粉中的掺假情况进行了定量分析。该研究方法不仅在检测特种奶粉掺假方面具有重大前景,而且在分析其他粉状掺假物方面也显示出广泛的适用性。