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棕榈仁壳提取物作为1M盐酸溶液中碳钢腐蚀有效抑制剂的电化学、表面及理论研究

Electrochemical, surface, and theoretical investigations of palm kernel shell extract as an effective inhibitor for carbon-steel corrosion in 1 M HCl solution.

作者信息

Sanni Omotayo, Ren Jianwei, Jen Tien-Chien

机构信息

Department of Chemical Engineering, Faculty of Engineering, Built Environment and Information Technology, University of Pretoria, Pretoria, 0002, South Africa.

Department of Mechanical Engineering Science, University of Johannesburg, Cnr Kingsway and University Roads, Johannesburg, 2092, South Africa.

出版信息

Environ Sci Pollut Res Int. 2024 Oct 8. doi: 10.1007/s11356-024-35159-9.

Abstract

Herein, we employed palm kernel shell extract (PKSE) as an eco-friendly inhibitor for carbon steel in acidic-induced corrosion. The corrosion inhibition of PKSE on carbon steel in 1 M HCI solution was investigated by electrochemical impedance spectroscopy, weight loss, and potentiodynamic polarization measurements. The surface was characterized by scanning electron microscopy equipped with energy-dispersive X-ray spectroscopy. Moreover, the elastic modulus and hardness tests were conducted. Weight loss measurements revealed that the optimum concentration of inhibitors is 500 ppm with 95.3% inhibition efficiency in 1 M HCl solution. Electrochemical results showed that the inhibitor could exhibit excellent corrosion inhibition performance and displayed mixed-type inhibition. The electrochemical impedance spectroscopy analysis shows that the inhibition performance increases by increasing the concentration of PKSE. The surface studies ensure the PKSE effectiveness in carbon steel surface damage reduction. Also, the adsorption of PKSE molecules on the carbon steel surface occurs according to the Langmuir isotherm model. The primary goal of this investigation was the utilization of palm kernel shell extract as corrosion inhibitor for 1018 low carbon steel in 1 M HCl solution, which highlights its novelty. The present results will be helpful to uncover the versatile importance of palm kernel shell compounds in the corrosion inhibition process.

摘要

在此,我们使用棕榈壳提取物(PKSE)作为碳钢在酸性诱导腐蚀中的一种环保型缓蚀剂。通过电化学阻抗谱、失重法和动电位极化测量研究了PKSE在1M HCl溶液中对碳钢的缓蚀作用。用配备能量色散X射线光谱仪的扫描电子显微镜对表面进行了表征。此外,还进行了弹性模量和硬度测试。失重测量结果表明,缓蚀剂的最佳浓度为500ppm,在1M HCl溶液中的缓蚀效率为95.3%。电化学结果表明该缓蚀剂能表现出优异的缓蚀性能并呈现混合型缓蚀。电化学阻抗谱分析表明,随着PKSE浓度的增加,缓蚀性能增强。表面研究证实了PKSE在减少碳钢表面损伤方面的有效性。此外,PKSE分子在碳钢表面的吸附符合朗缪尔等温线模型。本研究的主要目的是将棕榈壳提取物用作1M HCl溶液中1018低碳钢的缓蚀剂,这突出了其新颖性。目前的结果将有助于揭示棕榈壳化合物在缓蚀过程中的多种重要性。

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