Extreme Anomalous Conductance Enhancement in Neutral Diradical Acene-like Molecular Junctions.

We achieve, at room temperature, conductance enhancements over 2 orders of magnitude in single molecule circuits formed with polycyclic benzoquinoidal () diradicals upon increasing molecular length by ∼5 Å. We find that this extreme and atypical anti-ohmic conductance enhancement at longer molecular lengths is due to the diradical character of the molecules, which can be described as a topologically nontrivial electronic state, and results in constructive interference between the frontier molecular orbitals. The distinct feature of the compounds studied here as molecular wires is that they are characterized by moderate diradical character in the neutral state, allowing for robust and facile measurements of their transport properties. We adapt the 1D-SSH model, originally developed to examine electronic topological order in linear carbon chains, to the polycyclic systems studied here and find that it captures the anti-ohmic trends in this molecular series. Specifically, our model reveals that the mechanism of conductance enhancement with length in polycyclic systems is constructive quantum interference between the frontier orbitals with nontrivial topology, which is present in acene-like, but not in linear, molecular systems. Importantly, we use our model to predict and experimentally validate that anti-ohmic trends can be engineered through synthetic adjustments of the diradical character of the acene-like molecules. Overall, we achieve extreme anti-ohmic enhancement and mechanistic insight into electronic transport in a class of materials that we identify here as promising candidates for creating highly conductive and tunable nanoscale wires.