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TiO 薄膜在石英管内壁的制备及光降解。

Preparation and Photodegradation of TiO Thin Films on the Inner Wall of Quartz Tubes.

机构信息

College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China.

Analysis and Test Center, Beijing University of Chemical Technology, Beijing 100029, China.

出版信息

Int J Mol Sci. 2024 Sep 24;25(19):10253. doi: 10.3390/ijms251910253.

Abstract

Titanium dioxide thin films on the inner wall of quartz tubes were prepared in situ by the sol-gel method. Meanwhile, copper and cerium were loaded onto the surface of the titanium dioxide thin films to enhance photocatalytic activity and broaden the range of light absorption. X-ray diffractometer, X-ray photoelectron spectroscopy, scanning electron microscopy, energy dispersive X-ray spectrum, N gas adsorption, UV diffuse reflectance spectroscopy, electron paramagnetic resonance, photoluminescene spectroscopy, and so on were used to characterize the structure, morphology, chemical composition, and optical properties of the prepared photocatalyst. Methylene blue (MB) was used as a simulated organic pollutant to study the photocatalytic performance of the photocatalyst, which was a translucent, structurally stable, and reusable high-efficiency photocatalytic catalyst. Under UV lamp irradiation, the MB photodegradation efficiency was 94.5%, which reached 91.2% after multiple cycles.

摘要

在石英管内壁原位采用溶胶-凝胶法制备二氧化钛薄膜,同时将铜和铈负载到二氧化钛薄膜表面,以提高光催化活性和拓宽光吸收范围。采用 X 射线衍射仪、X 射线光电子能谱、扫描电子显微镜、能谱仪、N 气体吸附、紫外漫反射光谱、电子顺磁共振、光致发光光谱等对所制备的催化剂进行结构、形貌、化学组成和光学性能的表征。亚甲基蓝(MB)被用作模拟有机污染物,以研究催化剂的光催化性能,该催化剂是一种半透明、结构稳定、可重复使用的高效光催化催化剂。在紫外灯照射下,MB 的光降解效率达到 94.5%,经过多次循环后达到 91.2%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a513/11477359/4296ac63c4b4/ijms-25-10253-g001.jpg

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