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电极位置对含表面电解质的污染软黏土电动修复的影响

Effect of Electrode Positioning on Electrokinetic Remediation of Contaminated Soft Clay with Surface Electrolyte.

作者信息

Sun Zhaohua, Xu Shuwen, Zhang Jianming, Eugene Beukes Demarscho, Li Sheng

机构信息

School of Transportation and Civil Engineering, Nantong University, Nantong 226019, China.

Key Laboratory of New Technology for Construction of Cities in Mountain Area, Ministry of Education, Chongqing University, Chongqing 400045, China.

出版信息

Toxics. 2024 Oct 19;12(10):758. doi: 10.3390/toxics12100758.

Abstract

Soft clay contamination is an increasingly global issue with significant implications for land development and human health. Electrokinetic remediation (EKR) has demonstrated significant potential for cleaning contaminated soils. It is crucial to develop efficient processes that minimize environmental impact and reduce costs. A series of citric acid (CA)-enhanced EKR tests were conducted using a novel experimental setup, with the electrolyte positioned above the soil surface, to examine the impact of four different electrode arrangements on the effectiveness of EKR. The position of the electrode end had a significant impact on the migration of ions in the anolyte and catholyte, which in turn affected the volume reduction in the anolyte, the magnitude of the current, and the migration of heavy metals. The electrode arrangement mode (electrodes suspended in the electrolytes) can enhance the migration of the anolyte and reduce the drainage of the soil, making it an effective measure for improving the removal rate of heavy metals. After the heavy metal remediation is complete, the bearing capacity of the soil should be increased. Changing the electrode arrangement to mode (anode suspended in the anolyte, a very small part of the cathode inserted into the soil) is an effective measure for reducing the soil water content and improving soil strength.

摘要

软黏土污染是一个日益全球化的问题,对土地开发和人类健康有着重大影响。电动修复(EKR)已显示出在清理受污染土壤方面的巨大潜力。开发能将环境影响降至最低并降低成本的高效工艺至关重要。使用一种新颖的实验装置进行了一系列柠檬酸(CA)强化的EKR测试,其中电解质位于土壤表面上方,以研究四种不同电极布置对EKR有效性的影响。电极末端的位置对阳极电解液和阴极电解液中离子的迁移有重大影响,进而影响阳极电解液中的体积减少、电流大小以及重金属的迁移。电极布置模式(电极悬浮在电解液中)可以增强阳极电解液的迁移并减少土壤的排水,使其成为提高重金属去除率的有效措施。重金属修复完成后,应提高土壤的承载能力。将电极布置改为模式(阳极悬浮在阳极电解液中,阴极的一小部分插入土壤)是降低土壤含水量和提高土壤强度的有效措施。

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