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由回收纸浆纤维制备的疏水性生物基泡沫及其性能。

Hydrophobic bio-based foam prepared from recycled pulp fiber and its properties.

作者信息

Gao Yuting, Kong Chuikun, Lu Peng, Wu Rina

机构信息

Tianjin Key Laboratory of Pulp & Paper, State Key Laboratory of Biobased Fiber Manufacturing Technology, China Light Industry Key Laboratory of Papermaking and Biorefinery, School of light industry science and engineering, Tianjin University of Science & Technology, Tianjin 300457, China.

Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control, School of Light Industry and Food Engineering, Guangxi University, Nanning 530004, China.

出版信息

Int J Biol Macromol. 2024 Dec;282(Pt 3):136989. doi: 10.1016/j.ijbiomac.2024.136989. Epub 2024 Oct 28.

Abstract

Compared with traditional petroleum-based foam materials, cellulosic foam materials have significant advantages in terms of economy and environmental protection. However, the traditional cellulose-based foams have some problems such as high energy consumption in the preparation process. In this study, the recycled pulp foam (RPF) with ultra-light density (12.69 kg/m ~ 13.83 kg/m) and high porosity (99.07 % ~ 99.15 %) was prepared by mechanical stirring using waste corrugated cardboard as the main raw material and further hydrophobically modified using rosin. The prepared r-RPF foam has excellent hydrophobicity with the water contact angle remaining 132.9° after 20 s. In addition, the rosin coating enhances the mechanical properties of r-RPF, and the stress of r-RPF at 50 % strain is increased by 97 %. It should be noted that after rosin treatment, the compressive strength and elasticity of r-RPF were improved. The r-RPF was stable in water and had a high oil adsorption capacity (7.8 to 28.13 g/g), which had the potential to treat current oily wastewater.

摘要

与传统的石油基泡沫材料相比,纤维素基泡沫材料在经济和环保方面具有显著优势。然而,传统的纤维素基泡沫存在一些问题,例如制备过程中的高能耗。在本研究中,以废瓦楞纸板为主要原料,通过机械搅拌制备了具有超低密度(12.69 kg/m³13.83 kg/m³)和高孔隙率(99.07%99.15%)的再生纸浆泡沫(RPF),并进一步用松香进行疏水改性。制备的r-RPF泡沫具有优异的疏水性,20秒后水接触角保持在132.9°。此外,松香涂层增强了r-RPF的力学性能,r-RPF在50%应变时的应力提高了97%。需要注意的是,经过松香处理后,r-RPF的抗压强度和弹性得到了改善。r-RPF在水中稳定,具有较高的吸油能力(7.8至28.13 g/g),具有处理当前含油废水的潜力。

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