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用一个简单的微观力学模型量化白云母中的化学机械弱化。

Quantifying chemomechanical weakening in muscovite mica with a simple micromechanical model.

作者信息

Sickle Jordan J, Mook William M, DelRio Frank W, Ilgen Anastasia G, Wright Wendelin J, Dahmen Karin A

机构信息

Department of Physics and Anthony J. Leggett Institute for Condensed Matter Theory, University of Illinois at Urbana-Champaign, 1110 West Green Street, Urbana, IL, 61801, USA.

Microsystems Engineering, Science and Applications Center, Sandia National Laboratories, Albuquerque, NM, 87123, USA.

出版信息

Nat Commun. 2024 Nov 6;15(1):9552. doi: 10.1038/s41467-024-53213-5.

DOI:10.1038/s41467-024-53213-5
PMID:39505851
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11541873/
Abstract

In response to gradual nanoindentation, the surface of muscovite mica deforms by sudden stochastic nanometer-scale displacement bursts. Here, the statistics of these displacement events are interpreted using a statistical model previously used to model earthquakes to understand how chemically reactive environments alter the surface properties of this material. We show that the statistics of nanoindentation displacement bursts in muscovite mica are tuned by chemomechanical weakening in a manner similar to how the statistics of model events are tuned by a mechanical weakening parameter that describes how easily system-spanning cracks can be nucleated. Because the predictions of this model are independent of any surface defects or structural details, these results suggest this simple model can be universally used to describe chemomechanical weakening in many systems prone to slip avalanches on a wide range of spatio-temporal scales.

摘要

对于逐渐施加的纳米压痕,白云母云母的表面会通过突然的随机纳米级位移爆发而变形。在此,这些位移事件的统计数据使用先前用于模拟地震的统计模型进行解释,以了解化学反应环境如何改变这种材料的表面性质。我们表明,白云母云母中纳米压痕位移爆发的统计数据通过化学机械弱化进行调整,其方式类似于模型事件的统计数据通过一个机械弱化参数进行调整,该参数描述了跨越系统的裂纹成核的难易程度。由于该模型的预测与任何表面缺陷或结构细节无关,这些结果表明这个简单的模型可以普遍用于描述许多在广泛的时空尺度上容易发生滑动雪崩的系统中的化学机械弱化。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e84e/11541873/c77c8452afe0/41467_2024_53213_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e84e/11541873/4173ddb2ac98/41467_2024_53213_Fig1_HTML.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e84e/11541873/ea24e657494e/41467_2024_53213_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e84e/11541873/c77c8452afe0/41467_2024_53213_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e84e/11541873/4173ddb2ac98/41467_2024_53213_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e84e/11541873/43c673f83d2e/41467_2024_53213_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e84e/11541873/a6ce419183ba/41467_2024_53213_Fig3_HTML.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e84e/11541873/a9298f85d60a/41467_2024_53213_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e84e/11541873/ea24e657494e/41467_2024_53213_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e84e/11541873/c77c8452afe0/41467_2024_53213_Fig7_HTML.jpg

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本文引用的文献

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J Hazard Mater. 2024 Jul 5;472:134495. doi: 10.1016/j.jhazmat.2024.134495. Epub 2024 May 3.
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Frequency Dependent Silica Dissolution Rate Enhancement under Oscillating Pressure via an Electrochemical Pressure Solution-like, Surface Resonance Mechanism.基于电化学压溶似表面共振机制的压力波动下频率相关的二氧化硅溶解速率增强。
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Pop-In Phenomenon as a Fundamental Plasticity Probed by Nanoindentation Technique.
作为通过纳米压痕技术探究的一种基本可塑性的突入现象。
Materials (Basel). 2021 Apr 9;14(8):1879. doi: 10.3390/ma14081879.
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Array programming with NumPy.使用 NumPy 进行数组编程。
Nature. 2020 Sep;585(7825):357-362. doi: 10.1038/s41586-020-2649-2. Epub 2020 Sep 16.
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SciPy 1.0: fundamental algorithms for scientific computing in Python.SciPy 1.0:Python 中的科学计算基础算法。
Nat Methods. 2020 Mar;17(3):261-272. doi: 10.1038/s41592-019-0686-2. Epub 2020 Feb 3.
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Avalanche statistics from data with low time resolution.来自低时间分辨率数据的雪崩统计
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