Ding Guanzhi, Qin Guangzhi, Ying Wanying, Wang Pengyu, Yang Yang, Tang Chuanyang, Liu Qing, Li Minghui, Huang Ke, Chen Shuoping
College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, China.
Nanomaterials (Basel). 2024 Nov 20;14(22):1857. doi: 10.3390/nano14221857.
This study demonstrates, for the first time, the conversion of waste rice noodles (WRN) into a cost-effective, nano-silver-loaded activated carbon (Ag/AC) material capable of efficient adsorption and antibacterial activity. The fabrication process began with the conversion of WRN into hydrothermal carbon (HTC) via a hydrothermal method. Subsequently, the HTC was combined with silver nitrate (AgNO) and sodium hydroxide (NaOH), followed by activation through high-temperature calcination, during which AgNO was reduced to nano-Ag and loaded onto the HTC-derived AC, resulting in a composite material with both excellent adsorption properties and antibacterial activity. The experimental results indicated that the incorporation of nano-Ag significantly enhanced the specific surface area of the Ag/AC composite and altered its pore size distribution characteristics. Under optimized preparation conditions, the obtained Ag/AC material exhibited a specific surface area of 2025.96 m/g and an average pore size of 2.14 nm, demonstrating effective adsorption capabilities for the heavy metal Cr(VI). Under conditions of pH 2 and room temperature (293 K), the maximum equilibrium adsorption capacity for Cr(VI) reached 97.07 mg/g. The adsorption behavior of the resulting Ag/AC fitted the Freundlich adsorption isotherm and followed a pseudo-second-order kinetic model. Furthermore, the Ag/AC composite exhibited remarkable inhibitory effects against common pathogenic bacteria such as and , achieving antibacterial rates of 100% and 81%, respectively, after a contact time of 4 h. These findings confirm the feasibility of utilizing the HTC method to process WRN and produce novel AC-based functional materials.
本研究首次展示了将废弃米粉(WRN)转化为一种具有成本效益的、负载纳米银的活性炭(Ag/AC)材料,该材料具有高效吸附和抗菌活性。制备过程始于通过水热法将WRN转化为水热碳(HTC)。随后,将HTC与硝酸银(AgNO)和氢氧化钠(NaOH)混合,接着通过高温煅烧进行活化,在此过程中AgNO被还原为纳米银并负载到HTC衍生的AC上,从而得到一种兼具优异吸附性能和抗菌活性的复合材料。实验结果表明,纳米银的掺入显著提高了Ag/AC复合材料的比表面积,并改变了其孔径分布特征。在优化的制备条件下,所获得的Ag/AC材料的比表面积为2025.96 m²/g,平均孔径为2.14 nm,对重金属Cr(VI)表现出有效的吸附能力。在pH值为2和室温(293 K)的条件下,对Cr(VI)的最大平衡吸附容量达到97.07 mg/g。所得Ag/AC的吸附行为符合Freundlich吸附等温线,并遵循准二级动力学模型。此外,Ag/AC复合材料对常见病原菌如[具体细菌1]和[具体细菌2]表现出显著的抑制作用,接触4小时后,抗菌率分别达到100%和81%。这些发现证实了利用HTC方法处理WRN并生产新型AC基功能材料的可行性。