Schollmeyer Dieter, Kammler Claudia, Detert Heiner
University of Mainz, Department of Chemistry, Duesbergweg 10-14, 55099 Mainz, Germany.
IUCrdata. 2024 Nov 8;9(Pt 11):x241019. doi: 10.1107/S2414314624010198. eCollection 2024 Nov.
The thio-nocarbonate of -cyclo-octenediol, CHOS, crystallizes with a 9/1 disorder in the position of the and -enanti-omers. As a result of -annulation, both rings adopt a twist conformation.
-环辛烯二醇的硫代碳酸酯(CHOS)在α和β对映体的位置以9/1无序形式结晶。由于α-环化作用,两个环均呈现扭曲构象。