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生物炭功能化铜- l -组氨酸在氰化物化学和均相选择性转化为酰胺以及将硝基芳烃还原为苯胺中的催化应用

Catalytic Application of Biochar Functionalized Copper-l-histidine for the Chemo and Homoselective Conversion of Cyanides to Amides and Reduction of Nitroarenes to anilines.

作者信息

Farrokh Mahrokh, Hajjami Maryam, Zolfigol Mohammad Ali, Jalali-Mola Sepideh

机构信息

Department of Organic Chemistry, Faculty of Chemistry and Petroleum Sciences, Bu-Ali Sina University, Hamedan 6517838683, Iran.

出版信息

ACS Omega. 2024 Nov 19;9(48):47811-47821. doi: 10.1021/acsomega.4c08465. eCollection 2024 Dec 3.

Abstract

In our study, we aimed to use olive pomace, food industry waste, as biomass to produce biochar nanoparticles. The surface of the biochar was functionalized with the l-histidine ligand, and then cupric acetate was added to prepare Cu-l-histidine@biochar as a final catalyst for the chemo- and homoselective synthesis of amide and aniline derivatives. To characterize the novel catalyst, we employed various techniques. Another notable feature of this catalyst is its reusability, which maintained significant efficiency even after multiple uses in reactions.

摘要

在我们的研究中,我们旨在利用食品工业废料橄榄果渣作为生物质来制备生物炭纳米颗粒。用l-组氨酸配体对生物炭表面进行功能化处理,然后添加醋酸铜以制备Cu-l-组氨酸@生物炭,作为酰胺和苯胺衍生物化学选择性和均相选择性合成的最终催化剂。为了表征这种新型催化剂,我们采用了各种技术。这种催化剂的另一个显著特点是其可重复使用性,即使在反应中多次使用后仍保持显著的效率。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5f2c/11618395/5990fd388249/ao4c08465_0011.jpg

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