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用于水分解的贵金属基氧化物电催化剂的最新进展。

Recent achievements in noble metal-based oxide electrocatalysts for water splitting.

作者信息

Wang Feng, Xiao Linfeng, Jiang Yuwei, Liu Xijun, Zhao Xue, Kong Qingquan, Abdukayum Abdukader, Hu Guangzhi

机构信息

Xinjiang Key Laboratory of Novel Functional Materials Chemistry, College of Chemistry and Environmental Sciences, Kashi University, Kashi 844000, China.

Qilu Lake Field Scientific Observation and Research Station for Plateau Shallow Lake in Yunnan Province, Institute for Ecological Research and Pollution Control of Plateau Lakes, School of Ecology and Environmental Science, Yunnan University, Kunming 650504, China.

出版信息

Mater Horiz. 2025 Mar 17;12(6):1757-1795. doi: 10.1039/d4mh01315h.

Abstract

The search for sustainable energy sources has accelerated the exploration of water decomposition as a clean H production method. Among the methods proposed, H production water electrolysis has garnered considerable attention. However, the process of H production from water electrolysis is severely limited by the slow kinetics of the anodic oxygen evolution reaction and large intrinsic overpotentials at the anode; therefore, suitable catalysts need to be found to accelerate the reaction rate. Noble metal-based oxide electrocatalysts retain the advantages of abundant active sites, high electrical conductivity of noble metals, and low cost, which make them promising electrocatalysts; however, they suffer from the challenge of an imbalance between catalytic activity and stability. This review presents recent research progress in noble metals and their oxides as electrocatalysts. In this review, two half-reactions (the hydrogen evolution reaction and the oxygen evolution reaction) of water electrolysis are described. Recently reported methods for the synthesis of noble metal-based oxide electrocatalysts, improvement strategies, and sources of enhanced activity and stability for these types of catalysts are presented. Finally, the challenges and future perspectives in the field are summarised. This review is expected to help improve the understanding of noble metal-based oxide electrocatalysts.

摘要

对可持续能源的探索加速了对水分解作为一种清洁制氢方法的研究。在已提出的方法中,水电解制氢受到了广泛关注。然而,水电解制氢过程受到阳极析氧反应动力学缓慢和阳极较大固有过电位的严重限制;因此,需要找到合适的催化剂来加快反应速率。基于贵金属的氧化物电催化剂兼具活性位点丰富、贵金属导电性高和成本低等优点,使其成为有前景的电催化剂;然而,它们面临着催化活性与稳定性失衡的挑战。本文综述了贵金属及其氧化物作为电催化剂的最新研究进展。本文描述了水电解的两个半反应(析氢反应和析氧反应)。介绍了最近报道的基于贵金属的氧化物电催化剂的合成方法、改进策略以及这些类型催化剂活性和稳定性增强的来源。最后,总结了该领域的挑战和未来展望。本文有望有助于增进对基于贵金属的氧化物电催化剂的理解。

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