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熔盐法长期碳捕获后Ni 200合金磨损情况的评估

Evaluation of the Wear of Ni 200 Alloy After Long-Term Carbon Capture in Molten Salts Process.

作者信息

Palimąka Piotr, Pietrzyk Stanisław, Balcerzak Maciej, Żaba Krzysztof, Leszczyńska-Madej Beata, Jaskowska-Lemańska Justyna

机构信息

Department of Physical Chemistry and Metallurgy of Non-Ferrous Metals, Faculty of Non-Ferrous Metals, AGH University of Krakow, al. Adama Mickiewicza 30, 30-059 Cracow, Poland.

Department of Metal Working and Physical Metallurgy of Non-Ferrous Metals, Faculty of Non-Ferrous Metals, AGH University of Krakow, al. Adama Mickiewicza 30, 30-059 Cracow, Poland.

出版信息

Materials (Basel). 2024 Dec 23;17(24):6302. doi: 10.3390/ma17246302.

Abstract

Reducing CO emissions is one of the major challenges facing the modern world. The overall goal is to limit global warming and prevent catastrophic climate change. One of the many methods for reducing carbon dioxide emissions involves capturing, utilizing, and storing it at the source. The Carbon Capture in Molten Salts (CCMS) technique is considered potentially attractive and promising, although it has so far only been tested at the laboratory scale. This study evaluates the wear of the main structural components of a prototype for CO capture in molten salts-a device designed and tested in the laboratories of AGH University of Kraków. The evaluation focused on a gas barbotage lance and a reactor chamber (made from Nickel 200 Alloy), which were in continuous, long-term (800 h) contact with molten salts CaCl-CaF-CaO-CaCO at temperatures of 700-940 °C in an atmosphere of N-CO. The research used light microscopy, SEM, X-ray, computed tomography (CT), and 3D scanning. The results indicate the greatest wear on the part of the lance submerged in the molten salts (3.9 mm/year). The most likely wear mechanism involves grain growth and intergranular corrosion. Nickel reactions with the aggressive salt environment and its components cannot be ruled out. Additionally, the applied research methods enabled the identification of material discontinuities in the reactor chamber (mainly in welded areas), pitting on its surface, and uneven wear in different zones.

摘要

减少一氧化碳排放是现代世界面临的主要挑战之一。总体目标是限制全球变暖并防止灾难性的气候变化。减少二氧化碳排放的众多方法之一是在源头捕获、利用并储存它。熔盐中的碳捕获(CCMS)技术被认为具有潜在吸引力和前景,尽管到目前为止它仅在实验室规模进行了测试。本研究评估了熔盐中二氧化碳捕获原型的主要结构部件的磨损情况,该装置是在克拉科夫AGH大学实验室设计和测试的。评估重点关注气体鼓泡喷枪和反应室(由镍200合金制成),它们在700 - 940°C的温度下于N₂ - CO₂气氛中与CaCl₂ - CaF₂ - CaO - CaCO₃熔盐持续长期(800小时)接触。研究使用了光学显微镜、扫描电子显微镜、X射线、计算机断层扫描(CT)和3D扫描。结果表明,浸没在熔盐中的喷枪部分磨损最大(每年3.9毫米)。最可能的磨损机制包括晶粒长大和晶间腐蚀。不能排除镍与侵蚀性盐环境及其成分发生反应。此外,所应用的研究方法能够识别反应室中的材料不连续性(主要在焊接区域)、其表面的点蚀以及不同区域的不均匀磨损。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7624/11676382/9cc1a8a06414/materials-17-06302-g001.jpg

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