Volchenko Dmytro, Kernytskyy Ivan, Royko Yuriy, Ostashuk Mykola, Fidrovska Nataliia, Skrypnyk Vasyl, Zhuravlev Dmytro, Klochko Nataliia, Rys Vasyl, Berezovetska Oksana, Dixit Saurav, Stefańska Anna, Koda Eugeniusz, Singh Subhav, Sharma Kamal, Mahadeva Rajesh
Ivano-Frankivsk National Technical University of Oil and Gas, Ivano-Frankivsk, Ukraine.
Institute of Civil Engineering, Warsaw University of Life Sciences, Warsaw, Poland.
Sci Rep. 2025 Jan 25;15(1):3265. doi: 10.1038/s41598-025-86738-w.
The composition of the metal-polymer friction pair is carefully considered for interacting with water and hydrogen, ensuring the metals electrode process potential remains below waters in a neutral medium. Simultaneously, adherence to defined chemical composition ratios for the metal-polymer materials is crucial. This analysis is conducted under conditions of thermal stabilization, characterized by a minimal temperature gradient across the rim thickness within an equivalent thermal field. Using the quasi-chemical approximation, the paper derives a concentration-dependent diffusion coefficient of hydrogen (H) in iron (Fe) across a broad spectrum. This derivation includes electronic and vibrational contributions to the chemical potential. The research establishes a correlation between the equivalent diffusion coefficient and the concentration of diffusing hydrogen atoms from the metal, such as the pulley or drum rim. These findings offer novel insights into optimizing hydrogen wear behaviour in brake friction couples, contributing to advancements in materials and design considerations in the automotive field.
金属 - 聚合物摩擦副的组成经过精心考量,以便与水和氢相互作用,确保在中性介质中金属电极过程电位保持在水的电位以下。同时,严格遵守金属 - 聚合物材料的特定化学成分比例至关重要。该分析是在热稳定条件下进行的,其特征是在等效热场中沿轮辋厚度的温度梯度最小。本文采用准化学近似法,得出了氢(H)在铁(Fe)中的浓度依赖性扩散系数,涵盖了很宽的范围。这种推导包括了对化学势的电子和振动贡献。该研究建立了等效扩散系数与来自金属(如滑轮或鼓轮轮辋)的扩散氢原子浓度之间的相关性。这些发现为优化制动摩擦副中的氢磨损行为提供了新的见解,有助于推动汽车领域材料和设计考量方面的进展。