Wang Chen, Pi Ziqiang, Zheng Zhaoran, Chen Xing, Du Kaiping
BGRIMM TECHNOLOGY GROUP, Beijing, 100160, China.
BGRIMM Advanced Materials Science & Technology Co., Ltd, Beijing, 102206, China.
Sci Rep. 2025 Mar 4;15(1):7514. doi: 10.1038/s41598-025-92072-y.
Cemented carbides are widely used in cutting tools, wear-resistant parts and other fields. In order to further improve the mechanical properties, additives are usually added to cemented carbides. The interface bonding strength of additives with WC and Co phases will affect the crack propagation and have an important influence on the mechanical properties of cemented carbides. The gradient of electron work function (EWF) at the interface of WC/additive and Co/additive were obtained by atomic force microscope in this paper. According to the numerical relationship between the gradient of EWF and the interface bonding strength, the interface bonding strength of different additives and cemented carbide were qualitatively studied. The results show that in the interface of WC/additives, the interface bonding strength of WC/VC is the largest, followed by WC/TiC and WC/ZrO. In the interface of Co/additives, the interface bonding strength of Co/VC is the largest too, followed by Co/ZrO and Co/TiC, which verified the feasibility of this method in the field of cemented carbide.
硬质合金广泛应用于切削刀具、耐磨部件等领域。为了进一步提高其力学性能,通常会向硬质合金中添加添加剂。添加剂与WC和Co相的界面结合强度会影响裂纹扩展,对硬质合金的力学性能有重要影响。本文利用原子力显微镜获得了WC/添加剂和Co/添加剂界面处的电子功函数(EWF)梯度。根据EWF梯度与界面结合强度的数值关系,定性研究了不同添加剂与硬质合金的界面结合强度。结果表明,在WC/添加剂界面中,WC/VC的界面结合强度最大,其次是WC/TiC和WC/ZrO。在Co/添加剂界面中,Co/VC的界面结合强度也最大,其次是Co/ZrO和Co/TiC,验证了该方法在硬质合金领域的可行性。