Interactions in the fate of chemicals in terrestrial systems.

In outdoor lysimeters, [14C]atrazine (0.9 mg/kg dry soil), [14C]atrazine combined with the detergent n-dodecylbenzenesulfonate (0.9 and 10 mg/kg, respectively), [14C]n-dodecylbenzene-sulfonate (10 mg/kg), and [14C]n-dodecylbenzenesulfonate combined with atrazine (10 and 0.9 mg/kg, respectively) were applied to soils. Maize was grown in the first year and barley in the second year. n-Dodecylbenzenesulfonate increased the mobility of atrazine and its metabolites in soil as well as its leaching into water, its uptake by maize plants, and its volatilization from soil. Atrazine had a negative influence on mineralization, mobility in soil, leaching, plant uptake by both species, and binding rates of radiocarbon derived from the surfactant in soil and plants. The results were confirmed by short-term laboratory tests. Whereas the effects of the detergent on the fate of atrazine and its conversion products were apparent only in the first growing season, those of atrazine on the fate of detergent-derived residues could also be observed in the second year due to the persistence of atrazine in soil.