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采用化学镀镍磷(ENP)镀覆和高温热处理的表面处理方法增强气缸套的抗气蚀性能

Strengthening the Cavitation Resistance of Cylinder Liners Using Surface Treatment with Electroless Ni-P (ENP) Plating and High-Temperature Heat Treatment.

作者信息

Zhang Wenjuan, Gao Hao, Wang Qianting, Liu Dong, Zhang Enlai

机构信息

School of Mechanical and Electric Engineering, Sanming University, Sanming 365004, China.

SINOMACH Intelligence Technology Co., Ltd., Guangzhou 510700, China.

出版信息

Materials (Basel). 2025 Feb 28;18(5):1087. doi: 10.3390/ma18051087.

Abstract

As internal combustion engines (ICEs) develop towards higher explosion pressures and lower weights, their structures need to be more compact; thus, the wall thickness of their cylinder liners is reducing. However, intense vibrations in the cylinder liner can lead to coolant cavitation and, in severe cases, penetration of the liner, posing a significant reliability issue for ICEs. Therefore, research on cylinder liner cavitation has attracted increasing interest. Gray cast iron is widely used in cylinder liners for its hardness and wear resistance; however, additional surface plating is necessary to improve cavitation resistance. This study developed a novel surface-modification technology using electroless Ni-P plating combined with high-temperature heat treatment to create cylinder liners with refined grains, low weight loss rate, and high hardness. The heat-treatment temperature ranged from 100 to 600 °C. An ultrasonic cavitation tester was used to simulate severe cavitation conditions, and we analyzed and compared Ni-P-plated and heat-treated Ni-P-plated surfaces. The findings showed that the combination of Ni-P plating with high-temperature heat treatment led to smoother, more refined surface grains and the formation of cellular granular structures. After heat treatment, the plating structure converted from amorphous to crystalline. From 100 to 600 °C, the weight loss of specimens was within the range of 0.162% to 0.573%, and the weight loss (80.2% lower than the plated surface) and weight loss rate at 600 °C were the smallest. Additionally, cavitation resistance improved by 80.1%. The microhardness of the heat-treated plated surface reached 895 HV at 600 °C, constituting a 306 HV (65.8%) increase compared with that of the unplated surface, and a 560 HV increase compared with that of the maximum hardness of the plated surface without heat treatment of 335 HV, with an enhancement rate of 62.6%.

摘要

随着内燃机朝着更高的爆炸压力和更低的重量发展,其结构需要更加紧凑;因此,其气缸套的壁厚正在减小。然而,气缸套内强烈的振动会导致冷却液空化,在严重情况下会导致气缸套穿孔,这给内燃机带来了重大的可靠性问题。因此,对气缸套空化的研究引起了越来越多的关注。灰铸铁因其硬度和耐磨性而被广泛用于气缸套;然而,需要额外的表面镀层来提高抗空化性能。本研究开发了一种新颖的表面改性技术,采用化学镀镍磷与高温热处理相结合的方法,制造出具有细化晶粒、低失重率和高硬度的气缸套。热处理温度范围为100至600℃。使用超声空化测试仪模拟严重的空化条件,并对镀镍磷和热处理后的镀镍磷表面进行分析和比较。研究结果表明,镍磷镀层与高温热处理相结合导致表面晶粒更光滑、更细化,并形成蜂窝状颗粒结构。热处理后,镀层结构从非晶态转变为晶态。在100至600℃范围内,试样的失重率在0.162%至0.573%之间,600℃时的失重(比镀覆表面低80.2%)和失重率最小。此外,抗空化性能提高了80.1%。热处理后的镀覆表面在600℃时的显微硬度达到895 HV,与未镀覆表面相比提高了306 HV(65.8%),与未经热处理的镀覆表面最大硬度335 HV相比提高了560 HV,提高率为62.6%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e118/11901195/328bcd3530aa/materials-18-01087-g001.jpg

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