Zhang Yingzi, Zhang Mengxin, Zhang Jishu, Wu Jianbing, Peng Jiajia
School of Textile Garment & Design, Changshu Institute of Technology, Changshu 215500, China.
Polymers (Basel). 2025 Mar 27;17(7):905. doi: 10.3390/polym17070905.
Zinc oxide-modified tourmaline-based negative ion polyester fiber (ZnO/TM/PET), as a new functional fiber with excellent negative ion emission characteristics, is of great significance to human health, and its industrial application needs to be expanded and promoted. In this paper, using zinc oxide, tourmaline, and polyethylene terephthalate as the main raw materials, ZnO/TM/PET negative ion functional fiber with 5% ZnO/TM composites was prepared. Then, it was blended with cotton fiber and interknitted with wool yarn and spandex yarn, from which we developed five kinds of negative ion polyester/cotton-blended yarn and four different kinds of knitted double-sided fabric using different equipment and process parameters. The micromorphology of the fiber samples, the basic properties of the blended yarns, and the wearability and functional properties of the knitted fabrics were tested. The results show that the ZnO/TM negative ion additive is randomly dispersed in the polymer matrix without visible conglobation and the fiber has a good appearance. The blending ratio has an important effect on the properties of functional polyester/cotton blended yarn. The higher the ratio of negative ion polyester fiber in the blended yarn, the better the mechanical index of the blended yarn, the higher the negative ion emission, and the lower the hairiness index. The performances of fabric are influenced by the comprehensive action of fiber raw material type, yarn ratio, fabric tightness, and structure. The mechanical properties of the fabric knitted from negative ion polyester/cotton-blended yarn are lower than those made from negative ion polyester filament yarn. In the case of the same fabric structure, the negative ion emission performance, far-infrared emission performance, and antibacterial property of the fabric with a higher ratio of negative ion functional fiber is better than the lower ratio. With the same yarn composition, the negative ion emission performance and air permeability of the fabric with a loose structure are better than that of the fabric with a tight structure, but the moisture permeability, far-infrared emission properties, and antibacterial properties show little difference.
氧化锌改性电气石基负离子聚酯纤维(ZnO/TM/PET)作为一种具有优异负离子发射特性的新型功能纤维,对人体健康具有重要意义,其工业应用有待拓展和推广。本文以氧化锌、电气石和聚对苯二甲酸乙二酯为主要原料,制备了含5% ZnO/TM复合材料的ZnO/TM/PET负离子功能纤维。然后,将其与棉纤维混纺,并与羊毛纱线和氨纶纱线进行交织,利用不同的设备和工艺参数开发了五种负离子聚酯/棉混纺纱线和四种不同的针织双面织物。测试了纤维样品的微观形貌、混纺纱线的基本性能以及针织物的服用性能和功能性能。结果表明,ZnO/TM负离子添加剂随机分散在聚合物基体中,无明显团聚,纤维外观良好。混纺比对功能性聚酯/棉混纺纱线的性能有重要影响。混纺纱线中负离子聚酯纤维的比例越高,混纺纱线的力学指标越好,负离子发射量越高,毛羽指数越低。织物的性能受纤维原料类型、纱线比例、织物紧度和结构等综合作用的影响。负离子聚酯/棉混纺纱针织的织物力学性能低于负离子聚酯长丝针织的织物。在织物结构相同的情况下,负离子功能纤维比例较高的织物的负离子发射性能、远红外发射性能和抗菌性能优于比例较低的织物。在纱线组成相同的情况下,结构疏松的织物的负离子发射性能和透气性能优于结构紧密的织物,但透湿性能、远红外发射性能和抗菌性能差异不大。