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[不同类型湖泊中溶解性有机物光谱特征及来源的季节变化]

[Seasonal Variation in DOM Spectral Characteristics and Sources in Different Types of Lakes].

作者信息

Gao Jing-Tian, Tang Shi-Ke, Liu Wen-Li, Yu Feng-Ping, Zhang Peng, Li Wei-Ping

机构信息

School of Energy and Environment, Inner Mongolia University of Science and Technology, Baotou 014010, China.

Autonomous Region Collaborative Innovation Center for Ecological Protection and Comprehensive Utilization of Inner Mongolia Section of Yellow River Basin, Baotou 014010, China.

出版信息

Huan Jing Ke Xue. 2025 Apr 8;46(4):2154-2164. doi: 10.13227/j.hjkx.202401265.

Abstract

To study the spatio-temporal distribution characteristics and sources of dissolved organic matter (DOM) in different types of lakes, water samples were collected from the Wuliangsuhai Lake, Daihai Lake, and Nanhai Lake in Inner Mongolia in April and July 2023. The spectral characteristics and composition of DOM in the three lakes were analyzed using UV-vis spectroscopy, 3D fluorescence spectroscopy, and parallel factor analysis. Additionally, the response of DOM to water quality factors was explored. The results showed that the Daihai Lake had the highest DOM content among the three lakes. Compared to that during spring, the average concentration of dissolved organic carbon (DOC) during summer in the Wuliangsuhai Lake, Daihai Lake, and Nanhai Lake increased by 69.57%, 14.68%, and 85.88%, respectively. Additionally, the highest concentration of DOC in the Wuliangsuhai Lake increased from 15.32 mg·L in the northern region during spring to 25.73 mg·L in the central region during summer. The highest DOM concentration in the Daihai Lake was in the central region during spring with 56.12 mg·L DOC but in the western region during summer with 64.12 mg·L DOC. In the Nanhai Lake, the DOM in the inlet area was higher during spring, whereas it doubled in the outlet area during summer. Moreover, DOM in the Wuliangsuhai Lake showed the highest aromaticity and hydrophobicity, but lowest values were found in the Nanhai Lake. In addition, the humus of the three lakes mainly comprised fulvic acid. As for source, DOM was mainly endogenous during spring and exogenous during summer in the Wuliangsuhai Lake, while it was endogenous in the Daihai Lake and Nanhai Lake. Furthermore, the exogenous characteristics of DOM in the Daihai Lake were enhanced, while the endogenous characteristics of DOM in the Nanhai Lake were enhanced from spring to summer. Significant correlations were observed between DOM and TN, TP, and DO in the three lakes. The increase in TN, TP, and Chl-a in the Wuliangsuhai Lake and TN, TP, and COD in the Daihai Lake weakened the endogenous characteristics of DOM, whereas the increase in TN, Chl-a, DO, and COD in the Nanhai Lake enhanced the endogenous characteristics of DOM. The seasonal variation of spatial distribution and sources of DOM in different types of lakes were markedly influenced by hydrological conditions, external water input, biological activities, and human impacts.

摘要

为研究不同类型湖泊中溶解有机物(DOM)的时空分布特征及来源,于2023年4月和7月从内蒙古的乌梁素海、岱海和南海湖采集了水样。采用紫外可见光谱、三维荧光光谱和平行因子分析方法分析了三个湖泊中DOM的光谱特征和组成。此外,还探讨了DOM对水质因子的响应。结果表明,岱海的DOM含量在三个湖泊中最高。与春季相比,乌梁素海、岱海和南海湖夏季溶解有机碳(DOC)的平均浓度分别增加了69.57%、14.68%和85.88%。此外,乌梁素海春季北部地区DOC的最高浓度为15.32 mg·L,夏季中部地区增至25.73 mg·L。岱海春季DOM最高浓度出现在中部地区,DOC为56.12 mg·L,而夏季出现在西部地区,DOC为64.12 mg·L。在南海湖,春季进水口区域的DOM较高,而夏季出水口区域的DOM增加了一倍。此外,乌梁素海的DOM芳香性和疏水性最高,而南海湖的最低。此外,三个湖泊的腐殖质主要由富里酸组成。在来源方面,乌梁素海春季DOM主要为内源,夏季为外源,而岱海和南海湖为内源。此外,岱海DOM的外源特征增强,南海湖DOM的内源特征从春季到夏季增强。三个湖泊中DOM与TN、TP和DO之间存在显著相关性。乌梁素海TN、TP和Chl-a以及岱海TN、TP和COD的增加削弱了DOM的内源特征,而南海湖TN、Chl-a、DO和COD的增加增强了DOM的内源特征。不同类型湖泊中DOM的空间分布和来源的季节变化受到水文条件、外部水输入、生物活动和人类影响的显著影响。

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