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不同能量密度下全溶液处理非晶铟锌氧化物薄膜晶体管的固态激光退火

Solid-State Laser Annealing (SLA) of Fully Solution-Processed Amorphous InZnO Thin-Film Transistors at Various Fluence.

作者信息

Thazin Nu Myat, Bermundo Juan Paolo S, Hanifah Umu, Richter Johannes, Geburt Sebastian, Uraoka Yukiharu

机构信息

Division of Materials Science, Graduate School of Science and Technology, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara 630-0192, Japan.

Innovavent GmbH, Reinhard-Rube-Str. 4, Goettingen 37077, Germany.

出版信息

ACS Omega. 2025 Apr 3;10(14):14001-14009. doi: 10.1021/acsomega.4c10687. eCollection 2025 Apr 15.

Abstract

Advancing next-generation metal oxide thin film technologies demands the exploration of novel treatments for active materials. These treatments need to be processed via simple and cost-effective methods and low-temperature techniques to ensure compatibility with flexible substrates that are sensitive to high-temperature (>400 °C) annealing processes. To solve this problem, photoirradiation approaches on the active layers, such as ultraviolet treatment or excimer laser annealing (ELA), have been discovered as alternatives to conventional annealing techniques. The state-of-the-art ELA is limited primarily by its high-cost maintenance. Thus, we present an alternative photo-assisted approach to functionalize the amorphous Indium Zinc Oxide (a-IZO) films by employing solid-state laser annealing (SLA) post-treatment as an inexpensive option instead of the costly ELA process. The SLA approach can functionalize the a-IZO film to improve its film conductivity and function as the gate, source, and drain electrodes. After SLA post-treatment, a-IZO TFTs exhibited switching behavior with saturation mobility ( ) up to 0.98 cm V s and an on-off current ratio >10 at drain voltage, = 5.0 V. Therefore, this method holds the potential to serve as a viable alternative to the traditional annealing process or costly ELA technique with further refinement, especially for application in flexible devices.

摘要

推进下一代金属氧化物薄膜技术需要探索对活性材料的新型处理方法。这些处理需要通过简单且具有成本效益的方法以及低温技术来进行,以确保与对高温(>400°C)退火过程敏感的柔性基板兼容。为了解决这个问题,已发现对活性层进行光辐照的方法,如紫外线处理或准分子激光退火(ELA),可作为传统退火技术的替代方法。最先进的ELA主要受其高昂维护成本的限制。因此,我们提出了一种替代的光辅助方法,通过采用固态激光退火(SLA)后处理来使非晶铟锌氧化物(a-IZO)薄膜功能化,这是一种比昂贵的ELA工艺更便宜的选择。SLA方法可以使a-IZO薄膜功能化,以提高其薄膜导电性,并用作栅极、源极和漏极电极。经过SLA后处理后,a-IZO薄膜晶体管在漏极电压(V_D = 5.0 V)时表现出开关行为,饱和迁移率((\mu_s))高达(0.98 cm^2 V^{-1} s^{-1}),开/关电流比>10。因此,这种方法有潜力在进一步改进后成为传统退火工艺或昂贵的ELA技术的可行替代方案,特别是在柔性器件中的应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/595f/12004136/4915cf3bb1d8/ao4c10687_0001.jpg

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