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用于快速强力修复含尖锐分层裂纹的碳纤维增强塑料层压板的改性SC树脂预涂处理

Modified SC Resin Pre-Coating Treatment for Rapid and Robust Repair of CFRP Laminates with Sharp Delamination Cracks.

作者信息

Chen Yi, Ji Yi, Cheng Fei, Hu Xiaozhi

机构信息

School of Manufacturing Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, China.

Department of Mechanical Engineering, University of Western Australia, Perth, WA 6009, Australia.

出版信息

Polymers (Basel). 2025 Apr 16;17(8):1079. doi: 10.3390/polym17081079.

Abstract

A recent composite technique, namely Resin Pre-Coating (RPC), has demonstrated remarkably high effectiveness in the repair of Carbon Fiber-Reinforced Polymer (CFRP) composites. Compared to widely used scarf repair and injection repair, this non-destructive method offers advantages in addressing subsurface damages from the millimeter to micron scale, such as edge delaminations that frequently occur due to machining or low-energy impacts. The acetone-rich RPC solution can spontaneously transport sticky resin and other toughening agents into defects through capillary action. In this study, we further improved the solution by adopting a self-curing resin (i.e., SC-RPC), reducing the repair duration from the initial 2-3 months to merely a few hours. Using this modified solution, the CFRP specimens prepared containing delamination cracks were largely restored, reaching up to 94.9% of the original compressive strength. With the additional incorporation of carbon nanotubes (CNTs), full restoration was achieved, as is evidenced by load-bearing capacities and overload failure modes comparable to those of pristine specimens. The findings of this study may help alleviate concerns regarding substandard post-repair performance and prolonged repair durations, which are frequently criticized in real-world CFRP maintenance projects. The preparation of two new formulations, SC-RPC and SC-RPC+CNT, along with the optimization of key parameters, was carefully detailed in the manuscript to ensure experimental reproducibility.

摘要

一种最新的复合技术,即树脂预涂覆(RPC),已在碳纤维增强聚合物(CFRP)复合材料修复中展现出极高的有效性。与广泛使用的斜面修复和注射修复相比,这种无损方法在处理从毫米到微米尺度的亚表面损伤方面具有优势,比如因加工或低能量冲击频繁出现的边缘分层。富含丙酮的RPC溶液能通过毛细作用自发地将粘性树脂和其他增韧剂输送到缺陷处。在本研究中,我们通过采用自固化树脂(即SC-RPC)进一步改进了该溶液,将修复时间从最初的2至3个月缩短至仅几个小时。使用这种改良溶液,制备的含分层裂纹的CFRP试样大部分得以恢复,抗压强度达到原始强度的94.9%。通过额外加入碳纳米管(CNT),实现了完全恢复,这从承载能力和过载失效模式与原始试样相当可以得到证明。本研究结果可能有助于缓解对修复后性能不达标准和修复时间过长的担忧,这在实际的CFRP维护项目中经常受到批评。手稿中详细阐述了两种新配方SC-RPC和SC-RPC + CNT的制备以及关键参数的优化,以确保实验的可重复性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/616c/12030740/a9e4f09dbe15/polymers-17-01079-g001.jpg

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