文献检索文档翻译深度研究
Suppr Zotero 插件Zotero 插件
邀请有礼套餐&价格历史记录

新学期,新优惠

限时优惠:9月1日-9月22日

30天高级会员仅需29元

1天体验卡首发特惠仅需5.99元

了解详情
不再提醒
插件&应用
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
高级版
套餐订阅购买积分包
AI 工具
文献检索文档翻译深度研究
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2025

Magnetic-Field-Assisted Fe Nanowire Conformable Aerogels Galvanically Displaced to Cu and Pt for Three-Dimensional Electrode Applications.

作者信息

Calabro Rosemary L, Longstaff Garret L, Tang Edward M, Xiao Veronika M, Zammit Alexa S, Zhang Felita W, Nagelli Enoch A, Chapman Peter H, Lawton Timothy J, Allen Mark A, Losch Anchor R, Palmer Jesse L, Ciampa Alexander D, Burpeau Ian Z, Lucian Veronica M, Mandes Galen T, Bartolucci Stephen F, Maurer Joshua A, Burpo F John

机构信息

Department of Chemistry and Life Science, United States Military Academy, West Point, New York 10996 , United States.

U.S. Army Combat Capabilities Development Command-Armaments Center, Watervliet Arsenal, New York 12189, United States.

出版信息

ACS Appl Mater Interfaces. 2025 May 7;17(18):26854-26870. doi: 10.1021/acsami.5c00693. Epub 2025 Apr 27.


DOI:10.1021/acsami.5c00693
PMID:40289324
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12067370/
Abstract

There is an increasing need for free-standing, conformal electrodes for practical energy storage devices. To address this, we demonstrate the magnetic-field-assisted synthesis of interpenetrating Fe nanowire (FeNW) gels without the use of templates or composite scaffold material over a range of magnetic fields. In either a wet gel or a supercritical dried state as an aerogel, the FeNWs may be pressed into thin or conformal films. Varying the applied magnetic field strength with a solenoid during chemical synthesis resulted in increased nanowire length and local orientation of the FeNWs with increasing magnetic field strength, with approximately 80 nm diameters across field strengths of 0-150 mT. Flowing KPtCl or CuSO·5HO solutions through the wet iron gels to achieve the near complete galvanic displacement of iron to the more noble [PtCl] and Cu ions resulted in either platinum nanotubes (PtNTs) or copper nanowires (CuNWs) while maintaining a percolating network structure. Similar to the FeNW gels, the PtNT and CuNW gels were able to be supercritical dried and/or pressed into thin or conformal electrode films. CuNW and PtNT films demonstrated good potential as capacitive and oxygen reduction reaction electrodes, respectively. The magnetic-field-assisted synthesis of ferromagnetic iron nanowires offers a simple, rapid, and tunable method that, when combined with galvanic displacement with more noble metal ions, may enable a wide range of metal, alloy, and multimetallic nanowires and nanotubes for energy storage, sensing, and catalytic applications.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/8b79cb221723/am5c00693_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/64176fe8010b/am5c00693_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/33f085d4b4e3/am5c00693_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/26d714f5a21d/am5c00693_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/21fcc147eb75/am5c00693_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/34e689124ed7/am5c00693_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/f2c3557f7595/am5c00693_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/5a60b99e7f29/am5c00693_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/8f51e769f71a/am5c00693_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/8b79cb221723/am5c00693_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/64176fe8010b/am5c00693_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/33f085d4b4e3/am5c00693_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/26d714f5a21d/am5c00693_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/21fcc147eb75/am5c00693_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/34e689124ed7/am5c00693_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/f2c3557f7595/am5c00693_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/5a60b99e7f29/am5c00693_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/8f51e769f71a/am5c00693_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcfa/12067370/8b79cb221723/am5c00693_0009.jpg

相似文献

[1]
Magnetic-Field-Assisted Fe Nanowire Conformable Aerogels Galvanically Displaced to Cu and Pt for Three-Dimensional Electrode Applications.

ACS Appl Mater Interfaces. 2025-5-7

[2]
Platinum-coated copper nanowires with high activity for hydrogen oxidation reaction in base.

J Am Chem Soc. 2013-8-29

[3]
Robust and Stable Cu Nanowire@Graphene Core-Shell Aerogels for Ultraeffective Electromagnetic Interference Shielding.

Small. 2018-6

[4]
Copper Nanowire-Based Aerogel with Tunable Pore Structure and Its Application as Flexible Pressure Sensor.

ACS Appl Mater Interfaces. 2017-4-17

[5]
Multisegmented FeCo/Cu nanowires: electrosynthesis, characterization, and magnetic control of biomolecule desorption.

ACS Appl Mater Interfaces. 2015-4-8

[6]
Cellulose Nanofiber-Alginate Biotemplated Cobalt Composite Multifunctional Aerogels for Energy Storage Electrodes.

Gels. 2023-11-11

[7]
All-Solution-Processed Thermally and Chemically Stable Copper-Nickel Core-Shell Nanowire-Based Composite Window Electrodes for Perovskite Solar Cells.

ACS Appl Mater Interfaces. 2018-8-30

[8]
Advancements in Copper Nanowires: Synthesis, Purification, Assemblies, Surface Modification, and Applications.

Small. 2018-6

[9]
Noble metal aerogels-synthesis, characterization, and application as electrocatalysts.

Acc Chem Res. 2015-2-17

[10]
Facile Synthesis of Ultralong and Thin Copper Nanowires and Its Application to High-Performance Flexible Transparent Conductive Electrodes.

Nanoscale Res Lett. 2018-3-7

本文引用的文献

[1]
Nanofiber-Reinforced MXene/rGO Composite Aerogel for a High-Performance Piezoresistive Sensor and an All-Solid-State Supercapacitor Electrode Material.

ACS Appl Mater Interfaces. 2024-6-26

[2]
Magnetic aerogels from FePt and CoPt directly from organic solution.

Nanoscale. 2024-2-22

[3]
Bimetallic Pd-Co Aerogel Three-Dimensional Architecture: Developing Self-Assembled Materials for Advanced Ethanol Oxidation.

ACS Omega. 2023-11-22

[4]
Cellulose Nanofiber-Alginate Biotemplated Cobalt Composite Multifunctional Aerogels for Energy Storage Electrodes.

Gels. 2023-11-11

[5]
Mechanically Strengthened Aerogels through Multiscale, Multicompositional, and Multidimensional Approaches: A Review.

Adv Mater. 2024-5

[6]
CuO metallic aerogels with a tailored nodular morphology.

Dalton Trans. 2023-10-17

[7]
Galvanic Replacement Reaction: Enabling the Creation of Active Catalytic Structures.

ACS Appl Mater Interfaces. 2023-9-6

[8]
Reaction stoichiometry directs the architecture of trimetallic nanostructures produced galvanic replacement.

Nanoscale. 2023-2-23

[9]
Laser-assisted synthesis of Au aerogel with high-index facets for ethanol oxidation.

Nanotechnology. 2022-3-10

[10]
Patterning of Metal Nanowire Networks: Methods and Applications.

ACS Appl Mater Interfaces. 2021-12-29

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

推荐工具

医学文档翻译智能文献检索