Calabro Rosemary L, Longstaff Garret L, Tang Edward M, Xiao Veronika M, Zammit Alexa S, Zhang Felita W, Nagelli Enoch A, Chapman Peter H, Lawton Timothy J, Allen Mark A, Losch Anchor R, Palmer Jesse L, Ciampa Alexander D, Burpeau Ian Z, Lucian Veronica M, Mandes Galen T, Bartolucci Stephen F, Maurer Joshua A, Burpo F John
Department of Chemistry and Life Science, United States Military Academy, West Point, New York 10996 , United States.
U.S. Army Combat Capabilities Development Command-Armaments Center, Watervliet Arsenal, New York 12189, United States.
ACS Appl Mater Interfaces. 2025 May 7;17(18):26854-26870. doi: 10.1021/acsami.5c00693. Epub 2025 Apr 27.
There is an increasing need for free-standing, conformal electrodes for practical energy storage devices. To address this, we demonstrate the magnetic-field-assisted synthesis of interpenetrating Fe nanowire (FeNW) gels without the use of templates or composite scaffold material over a range of magnetic fields. In either a wet gel or a supercritical dried state as an aerogel, the FeNWs may be pressed into thin or conformal films. Varying the applied magnetic field strength with a solenoid during chemical synthesis resulted in increased nanowire length and local orientation of the FeNWs with increasing magnetic field strength, with approximately 80 nm diameters across field strengths of 0-150 mT. Flowing KPtCl or CuSO·5HO solutions through the wet iron gels to achieve the near complete galvanic displacement of iron to the more noble [PtCl] and Cu ions resulted in either platinum nanotubes (PtNTs) or copper nanowires (CuNWs) while maintaining a percolating network structure. Similar to the FeNW gels, the PtNT and CuNW gels were able to be supercritical dried and/or pressed into thin or conformal electrode films. CuNW and PtNT films demonstrated good potential as capacitive and oxygen reduction reaction electrodes, respectively. The magnetic-field-assisted synthesis of ferromagnetic iron nanowires offers a simple, rapid, and tunable method that, when combined with galvanic displacement with more noble metal ions, may enable a wide range of metal, alloy, and multimetallic nanowires and nanotubes for energy storage, sensing, and catalytic applications.
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