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包含香蕉叶活性炭和有机粘土以增强染料去除效果的可持续海藻酸钠水凝胶。

Sustainable sodium alginate hydrogels incorporating banana leaf activated carbon and organo-clay for enhanced dye removal.

作者信息

Arafa Esraa G, Gawad Omayma Fawzy Abdel, Eldin Zienab E, Ibrahim Marina Medhat, Abd-Elghafour Shimaa Ahmed, Osman Ali H M

机构信息

Department of Chemistry, Faculty of Science, Beni-Suef University, Beni-Suef, 62511, Egypt.

Chemistry Department, Faculty of Science, Beni-Suef University, Salah Salim St., Beni- Suef, 62514, Egypt.

出版信息

Sci Rep. 2025 May 9;15(1):16197. doi: 10.1038/s41598-025-99343-8.

Abstract

New sodium alginate-based hydrogels using activated carbon from banana leaves and organo-modified montmorillonite for water treatment. Activated carbon extracted successfully from banana leaves and montmorillonite clay was surface-modified using cetyltrimethylammonium bromide as a cationic surfactant. Hydrogels were then synthesized using calcium chloride as the cross-linking agent. They were characterized using FTIR, X-ray diffraction, and scanning electronic microscopy. Characterization intimated the incorporation of components successfully. Adsorption performance was determined using pH, adsorbent dosages, initial dye concentration, and contact time. Sodium alginate-based hydrogels demonstrated remarkable efficacy in removing MB and EBT dyes from synthetic solutions, achieving removal efficiencies of up to 80.3% and 84.9% respectively within 90 min at pH 7. The adsorption process corresponded better to the Freundlich isotherm model. The kinetics of EBT dye removal were described by a pseudo-second-order model. Meanwhile, the kinetics of the removal of MB dyes were described by both pseudo-first order and intraparticle diffusion models. We conducted MTT assays to determine the cytotoxicity of our blends. This showed a dose-dependent drop in viability. Sodium alginate-based hydrogels made the cells least cytotoxic. The developed hydrogels can be used as safe and effective agents for water treatment, as indicated by the results.

摘要

新型基于海藻酸钠的水凝胶,采用香蕉叶活性炭和有机改性蒙脱石用于水处理。成功从香蕉叶中提取的活性炭和蒙脱石粘土用十六烷基三甲基溴化铵作为阳离子表面活性剂进行表面改性。然后使用氯化钙作为交联剂合成水凝胶。使用傅里叶变换红外光谱(FTIR)、X射线衍射和扫描电子显微镜对其进行表征。表征表明各组分成功掺入。使用pH值、吸附剂用量、初始染料浓度和接触时间来测定吸附性能。基于海藻酸钠的水凝胶在从合成溶液中去除亚甲基蓝(MB)和铬黑T(EBT)染料方面表现出显著效果,在pH值为7时,90分钟内去除效率分别高达80.3%和84.9%。吸附过程更符合弗伦德里希等温线模型。EBT染料去除动力学由准二级模型描述。同时,MB染料去除动力学由准一级模型和颗粒内扩散模型共同描述。我们进行了MTT试验以确定我们的混合物的细胞毒性。结果显示活力呈剂量依赖性下降。基于海藻酸钠的水凝胶使细胞的细胞毒性最小。结果表明,所开发的水凝胶可作为安全有效的水处理剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d386/12064740/507652ab6f86/41598_2025_99343_Fig1_HTML.jpg

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