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冷等离子体作为一种新兴的石油改性催化途径。

Cold plasma as an emerging catalytic route for oil modification.

作者信息

Keramat Malihe, Golmakani Mohammad-Taghi

机构信息

Department of Food Science and Technology, Faculty of Agriculture, Fasa University, Fasa, Iran.

Department of Food Science and Technology, School of Agriculture, Shiraz University, Shiraz, Iran.

出版信息

Food Chem X. 2025 Apr 23;27:102493. doi: 10.1016/j.fochx.2025.102493. eCollection 2025 Apr.

Abstract

The effect of cold plasma on the oxidation, hydrogenation, transesterification, and pyrolysis reactions is investigated. Also, the effect of cold plasma parameters on these reactions and the advantages and challenges of cold plasma are investigated. Cold plasma can produce low-trans partial hydrogenated oil at low temperature without catalyst. Besides, oil modified through transesterification and pyrolysis processes using cold plasma technique can be used for biofuel production. Oxidation during cold plasma treatment can be inhibited by omitting the oxygen from carrier gas and applying the lowest possible input power and treatment time. One of the main challenges of using dielectric barrier discharge device at large scale is providing high plasma intensity for large amounts of raw materials. In microwave discharge plasma device, high capital investment is the main challenge for scaling up. In conclusion, cold plasma technique can hydrogenate and transesterify oils at low temperature.

摘要

研究了冷等离子体对氧化、氢化、酯交换和热解反应的影响。此外,还研究了冷等离子体参数对这些反应的影响以及冷等离子体的优点和挑战。冷等离子体可以在低温下无催化剂地生产低反式部分氢化油。此外,通过使用冷等离子体技术经酯交换和热解过程改性的油可用于生物燃料生产。通过从载气中去除氧气并施加尽可能低的输入功率和处理时间,可以抑制冷等离子体处理过程中的氧化。大规模使用介质阻挡放电装置的主要挑战之一是为大量原材料提供高等离子体强度。在微波放电等离子体装置中,高资本投资是扩大规模的主要挑战。总之,冷等离子体技术可以在低温下对油进行氢化和酯交换。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fd4/12063034/eba2dd7f0788/ga1.jpg

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