Hsiao Tzu-Chieh, Wang Wei-Han, Shih Yu-Ching, Chang Sih-Wei, Chen Hsuen-Li
Department of Materials Science and Engineering, National Taiwan University, Taipei 10617, Taiwan.
Center of Atomic Initiative for New Materials, National Taiwan University, Taipei 10617, Taiwan.
ACS Appl Mater Interfaces. 2025 Jun 4;17(22):32181-32193. doi: 10.1021/acsami.5c01072. Epub 2025 May 21.
A new trilayered structure design of metallic glass film was proposed and demonstrated to achieve near-perfect dual-band-selective absorptions within mid-wavelength infrared (MWIR) and long-wavelength infrared (LWIR) bands in atmospheric windows. A metal-insulator-metal (MIM) structure was used as a selective absorber for decades; however, due to the highly reflective properties of metal in the infrared region, the structure was difficult to apply within the mid- and long-infrared region. By applying the metallic glass film as a top layer, the asymmetric metallic glass-insulator-metal (MGIM) structure could display remarkably high absorptance in the mid-IR region, a distinct feature that a conventional metal-insulator-metal (MIM) structure could not achieve. In addition, the MGIM structure exhibited outstanding omnidirectional properties. The fabricated MGIM structure exhibited near-unity absorptions within MWIR and LWIR atmospheric windows, with an absorptance of 96.7% and 98.8% at peak wavelengths of 3.9 and 10.8 μm, respectively. These remarkable characteristics of the AlNiY-based MGIM structure make it highly promising for heat dissipation applications. The MGIM structure showed better radiative cooling performance than typical MIM emitters and an ideal broadband emitter. Furthermore, compared with other dual-band emitters that utilize complex metamaterial structures, the lithography-free process of our approach dramatically reduces the cost and simplifies the processes.
提出并展示了一种金属玻璃薄膜的新型三层结构设计,以在大气窗口的中波长红外(MWIR)和长波长红外(LWIR)波段内实现近乎完美的双波段选择性吸收。几十年来,金属-绝缘体-金属(MIM)结构一直被用作选择性吸收体;然而,由于金属在红外区域具有高反射特性,该结构难以应用于中红外和长红外区域。通过将金属玻璃薄膜用作顶层,非对称金属玻璃-绝缘体-金属(MGIM)结构在中红外区域可呈现出极高的吸收率,这是传统金属-绝缘体-金属(MIM)结构无法实现的显著特征。此外,MGIM结构还表现出出色的全向特性。所制备的MGIM结构在MWIR和LWIR大气窗口内呈现出近乎单位吸收率,在3.9和10.8μm的峰值波长处,吸收率分别为96.7%和98.8%。基于AlNiY的MGIM结构的这些显著特性使其在散热应用方面极具潜力。MGIM结构显示出比典型MIM发射器和理想宽带发射器更好的辐射冷却性能。此外,与其他利用复杂超材料结构的双波段发射器相比,我们方法的无光刻工艺极大地降低了成本并简化了流程。