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迈向可持续的聚氨酯替代品：非异氰酸酯聚氨酯（NIPUs）的合成、应用及生命周期综述。

Toward Sustainable Polyurethane Alternatives: A Review of the Synthesis, Applications, and Lifecycle of Non-Isocyanate Polyurethanes (NIPUs).

作者信息

Balla Evangelia, Bikiaris Dimitrios N, Pardalis Nikolaos, Bikiaris Nikolaos D

机构信息

Laboratory of Polymer Chemistry and Technology, Department of Chemistry, Aristotle University of Thessaloniki, GR54124 Thessaloniki, Greece.

出版信息

Polymers (Basel). 2025 May 16;17(10):1364. doi: 10.3390/polym17101364.

DOI:10.3390/polym17101364
PMID:40430660
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12114677/
Abstract

In recent decades, scientific interest has increasingly focused on sustainable and green polymers. Within this context, considerable efforts have been devoted to the synthesis and exploration of eco-friendly non-isocyanate polyurethanes (NIPUs) as alternatives to conventional polyurethanes (PUs), solving the problem of isocyanate toxicity and other environmental problems that existed. This review article highlights the synthetic pathways of NIPUs and identifies the potential hazards associated with their production and end-of-life (EoL) stages. While in the literature there are several reviews regarding the synthesis of NIPUs, the current work distinguishes itself by providing a comprehensive summary of the latest research on NIPUs, with a particular focus on their lifecycle management, recyclability, and the challenges that hinder their scalability for industrial-level production. Advances in NIPU synthesis have made them strong candidates for a diverse range of applications. This review underscores the most notable examples of these advancements, emphasizing their potential to drive sustainable polymer development.

摘要

近几十年来，科学兴趣越来越集中在可持续和绿色聚合物上。在此背景下，人们付出了巨大努力来合成和探索生态友好型非异氰酸酯聚氨酯（NIPUs），以替代传统聚氨酯（PUs），解决异氰酸酯毒性问题和其他现存的环境问题。这篇综述文章重点介绍了NIPUs的合成途径，并确定了与其生产和生命周期结束（EoL）阶段相关的潜在危害。虽然文献中有几篇关于NIPUs合成的综述，但当前的工作通过全面总结NIPUs的最新研究而脱颖而出，特别关注其生命周期管理、可回收性以及阻碍其实现工业规模生产扩大化的挑战。NIPU合成方面的进展使其成为各种应用的有力候选材料。本综述强调了这些进展中最显著的例子，强调了它们推动可持续聚合物发展的潜力。

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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ccf5/12114677/7be4e990a47f/polymers-17-01364-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ccf5/12114677/229bc7e46ed4/polymers-17-01364-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ccf5/12114677/23ccee4fc46e/polymers-17-01364-g014.jpg
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本文引用的文献

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2
Polyurethane Waste Recycling: Thermolysis of the Carbamate Fraction.聚氨酯废料回收：氨基甲酸酯部分的热解
ACS Omega. 2024 Oct 16;9(43):43438-43446. doi: 10.1021/acsomega.4c04671. eCollection 2024 Oct 29.
3
Preparation and Characterization of Glucose-Based Self-Blowing Non-Isocyanate Polyurethane (NIPU) Foams with Different Acid Catalysts.
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Polymers (Basel). 2024 Oct 15;16(20):2899. doi: 10.3390/polym16202899.
4
Cyclic carbamates based on (R)-(+)-limonene oxide for ring-opening polymerization.基于（R）-（+）-氧化柠檬烯的环状氨基甲酸酯用于开环聚合反应。
Sci Rep. 2024 Oct 9;14(1):23521. doi: 10.1038/s41598-024-73824-8.
5
Recycling of Polyurethane Foams via Glycolysis: A Review.通过醇解回收聚氨酯泡沫：综述
Materials (Basel). 2024 Sep 20;17(18):4617. doi: 10.3390/ma17184617.
6
Techno-economic Analysis and Life Cycle Assessment of Biomass-Derived Polyhydroxyurethane and Nonisocyanate Polythiourethane Production and Reprocessing.生物质衍生的聚羟基聚氨酯和非异氰酸酯聚硫脲的生产与再加工的技术经济分析及生命周期评估
ACS Sustain Chem Eng. 2024 Aug 1;12(32):12161-12170. doi: 10.1021/acssuschemeng.4c04046. eCollection 2024 Aug 12.
7
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