Porous Silica Gels Doped with Gold Nanoparticles: Preparation, Microstructure, Optical and Textural Properties.

Porous silica gel powders, doped with gold nanoparticles (AuNPs), were obtained by heating silica gels containing 1-dodecanethiol and tetrachloroauric acid at temperatures of 450 °C, 700 °C and 900 °C, and characterized using X-ray diffraction, TEM/EDS studies, UV/Vis reflectance spectroscopy and DTA/TG investigations. The color and microstructure of the obtained samples with a composition SiO:AuNPs (about 0.03% Au) depend on the heating temperature. The UV/Vis reflection spectra of the samples are explained using Mie's theory. The thermal stability of the obtained samples, as well as the processes occurring in the sol-gel matrix upon heating, were monitored by DTA/TG. The textural properties of the obtained materials were described based on adsorption-desorption isotherms. The obtained nanocomposites are promising pigments for ceramic glazes, similar to the Purple of Cassius. The textural properties of certain samples, = 200-350 m/g, a mean pore diameter () of approximately 10 nm and a specific pore volume () between 0.5 and 0.8 cm/g, make them promising candidates for catalytic applications, comparable to aerogel-like materials.