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己二酸行业一氧化二氮排放核算方法的进展

Advances in accounting methodology of nitrous oxide emissions from the adipic acid industry.

作者信息

He Shuwei, Han Yinghui, Qin Xiaodong

机构信息

College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 101408, China.

College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 101408, China; Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China.

出版信息

J Environ Sci (China). 2025 Nov;157:615-632. doi: 10.1016/j.jes.2024.03.014. Epub 2024 Mar 22.

Abstract

Nitrous oxide (NO), as an important gas affecting climate warming, is attracting attention from all walks of life. This review addresses NO emissions status in the adipic acid industry, a significant industrial greenhouse gas source. It elucidates the NO emission mechanism and influencing factors in adipic acid production. It extensively evaluates NO emission accounting methods, including Intergovernmental Panel on Climate Change (IPCC) Guidelines, World Resources Institute (WRI) Protocol, and others. While the IPCC emission factor method offers simplicity and comparability, it may lack precision for facilities with advanced emission reduction measures. To address this, a combined modeling and monitoring approach is advocated. It scrutinizes modeling methods (statistical techniques, Greenhouse Gas and Air Pollution Interactions and Synergies, and Life-cycle Assessment) and highlights their reliance on specific data and perspectives. It emphasizes the growing importance of on-site monitoring with mid-IR technology. Additionally, it underscores the potential of aircraft-based and satellite remote sensing for comprehensive NO emissions data. The review also highlights recent advancements in emission mitigation, particularly in adipic acid synthesis techniques, showing substantial potential for NO reduction. Innovative paradigms and strategies for NO mitigation in the adipic acid industry are presented, with a focus on achieving nitrogen oxides (NO) -free production. These approaches hold promise for emission reduction, given the high removal efficiency in plant end-of-treatment processes. Various accounting methods, monitoring techniques, and mitigation strategies were integrated and analyzed to provides a comprehensive overview of NO emissions in the adipic acid industry, with the aim of guiding future research and policy initiatives.

摘要

一氧化二氮(N₂O)作为一种影响气候变暖的重要气体,正受到各界关注。本综述阐述了己二酸行业(一个重要的工业温室气体源)的N₂O排放状况。它阐明了己二酸生产中的N₂O排放机制及影响因素。它广泛评估了N₂O排放核算方法,包括政府间气候变化专门委员会(IPCC)指南、世界资源研究所(WRI)协议等。虽然IPCC排放因子法具有简单性和可比性,但对于采取了先进减排措施的设施可能缺乏精确性。为解决这一问题,提倡采用建模与监测相结合的方法。它审视了建模方法(统计技术、温室气体与空气污染的相互作用和协同效应以及生命周期评估),并强调了它们对特定数据和观点的依赖。它强调了利用中红外技术进行现场监测的重要性日益增加。此外,它强调了基于飞机和卫星遥感获取全面N₂O排放数据的潜力。该综述还突出了近期减排方面的进展,特别是在己二酸合成技术方面,显示出大幅减少N₂O排放的潜力。提出了己二酸行业减排N₂O的创新模式和策略,重点是实现无氮氧化物(NO)生产。鉴于这些方法在工厂末端处理过程中的高去除效率,有望实现减排。综合分析了各种核算方法、监测技术和减排策略,以全面概述己二酸行业的N₂O排放情况,旨在指导未来的研究和政策举措。

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