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基于钒的MXenes：类型、合成及其在超级电容器应用中的最新进展

Vanadium-Based MXenes: Types, Synthesis, and Recent Advances in Supercapacitor Applications.

作者信息

Gao Zhiwei, Shi Donghu, Xu Jiawei, Hai Te, Zhao Yao, Qin Meng, Li Jian

机构信息

Hubei Key Laboratory of Energy Storage and Power Battery, School of Optoelectronic Engineering, School of New Energy, Hubei University of Automotive Technology, Shiyan 442002, China.

Hubei Key Laboratory of Energy Storage and Power Battery, School of Automotive Materials, Hubei University of Automotive Technology, Shiyan 442002, China.

出版信息

Nanomaterials (Basel). 2025 Jul 4;15(13):1038. doi: 10.3390/nano15131038.

DOI:10.3390/nano15131038
PMID:40648745
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12250767/
Abstract

Since the discovery of two-dimensional transition metal carbides and nitrides (MXenes), MXenes have attracted widespread research in the academic community due to their advantages, such as adjustable interlayer spacing, excellent hydrophilicity, conductivity, compositional diversity, and rich surface chemical composition. More than 100 different MXene combinations can be calculated theoretically, but only more than 40 have been successfully synthesized through experiments. Among the many synthesized and reported MXene materials, vanadium-based carbide MXenes, represented by VCT and VCT, show excellent application prospects in energy storage and have become the focus of researchers. In this review, we mainly discuss the structure, characteristics, and preparation methods of vanadium-based MXene precursors in the MAX phase and their applications in supercapacitors. Finally, we propose the main challenges existing at the current stage of vanadium-based materials and their heterostructures and provide a perspective on future research directions.

摘要

自从二维过渡金属碳化物和氮化物（MXenes）被发现以来，MXenes因其具有诸如可调节的层间距、优异的亲水性、导电性、成分多样性和丰富的表面化学成分等优点，在学术界引起了广泛的研究。理论上可以计算出100多种不同的MXene组合，但通过实验成功合成的只有40多种。在众多已合成并报道的MXene材料中，以VCT和VCT为代表的钒基碳化物MXenes在能量存储方面展现出优异的应用前景，成为研究人员关注的焦点。在这篇综述中，我们主要讨论MAX相钒基MXene前驱体的结构、特性、制备方法及其在超级电容器中的应用。最后，我们提出了钒基材料及其异质结构现阶段存在的主要挑战，并对未来的研究方向进行了展望。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/4e9613fc7246/nanomaterials-15-01038-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/ffebb1ffa4ff/nanomaterials-15-01038-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/f98d52133eb7/nanomaterials-15-01038-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/e75a03e46d39/nanomaterials-15-01038-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/e630dd08458e/nanomaterials-15-01038-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/58f10be9a671/nanomaterials-15-01038-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/fa27528a981d/nanomaterials-15-01038-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/b8f8a47a49bb/nanomaterials-15-01038-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/3865d0670a4e/nanomaterials-15-01038-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/894cd84655d9/nanomaterials-15-01038-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/4e9613fc7246/nanomaterials-15-01038-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/ffebb1ffa4ff/nanomaterials-15-01038-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/f98d52133eb7/nanomaterials-15-01038-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/e75a03e46d39/nanomaterials-15-01038-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/e630dd08458e/nanomaterials-15-01038-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/58f10be9a671/nanomaterials-15-01038-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/fa27528a981d/nanomaterials-15-01038-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/b8f8a47a49bb/nanomaterials-15-01038-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/3865d0670a4e/nanomaterials-15-01038-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/894cd84655d9/nanomaterials-15-01038-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/699c/12250767/4e9613fc7246/nanomaterials-15-01038-g010.jpg

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