Neagu Carina Sonia, Novac Andreea Codruta, Zaharia Cristian, Negrutiu Meda-Lavinia, Craciunescu Izabell, Socoliuc Vlad Mircea, Marin Catalin Nicolae, Bradu Ionela-Amalia, Nica Luminita Maria, Stef Marius, Duma Virgil-Florin, Romînu Mihai, Sinescu Cosmin
Department of Prosthetic Technology and Dental Materials, "Victor Babes" University of Medicine and Pharmacy Timisoara, 9 Revolutiei 1989 Ave., 300070 Timișoara, Romania.
Research Center in Dental Medicine Using Conventional and Alternative Technologies, "Victor Babes" University of Medicine and Pharmacy Timisoara, 9 Revolutiei 1989 Ave., 300070 Timișoara, Romania.
Medicina (Kaunas). 2025 Jul 17;61(7):1289. doi: 10.3390/medicina61071289.
: Dental adhesives augmented with magnetic nanoparticles (MNPs) have been proposed to prevent microleakages. MNPs dispersed in a dental adhesive reduce the thickness of the adhesive layer applied in a magnetic field and enhance the bond strength by favoring the penetration of the adhesive into dentinal tubules. However, the restoration's color has been found to be affected by the MNPs. This study tests the hypothesis that MNP coating can alleviate the esthetic impact of magnetic dental adhesives. : We synthesized FeO MNPs with silica coating (MNPs-SiO), calcium-based coating (MNPs-Ca), and no coating. Their morphology was studied using transmission electron microscopy (TEM) and scanning electron microscopy (SEM). Their chemical composition was assessed by energy-dispersive X-ray spectroscopy (EDX), and magnetic properties were measured using a vibrating sample magnetometer. FTIR spectroscopy was used to evaluate the polymerization of the MNP-laden adhesive. We prepared cavities in molar phantoms divided in four groups (n = 15 each) restored using the same adhesive with different MNP contents: Group 0 (G0)-no MNPs, G1-MNPs-SiO, G2-MNPs-Ca, and G3-uncoated MNPs. The restoration's color was quantified in the CIELAB color space using a dental spectrophotometer. : MNPs-SiO were globular, whereas MNPs-Ca had a cubic morphology. The SiO layer was 73.1 nm ± 9.9 nm thick; the Ca(OH) layer was 19.97 nm ± 2.27 nm thick. The saturation magnetization was 18.6 emu/g for MNPs-SiO, 1.0 emu/g for MNPs-Ca, and 65.7 emu/g for uncoated MNPs. MNPs had a marginal effect on the adhesive's photopolymerization. The mean color difference between G0 and G2 was close to the 50:50% acceptability threshold, whereas the other groups were far apart from G0. The mean whiteness index of G2 did not differ significantly from that of G0; G1 deviated marginally from G0, whereas G3 differed significantly from G0. : These results suggest that MNP coating can mitigate the influence of MNP-laden dental adhesives on the color of restorations.
已有人提出用磁性纳米颗粒(MNPs)增强牙科粘合剂以防止微渗漏。分散在牙科粘合剂中的MNPs可减小在磁场中施加的粘合剂层的厚度,并通过促进粘合剂渗入牙本质小管来增强粘结强度。然而,人们发现修复体的颜色会受到MNPs的影响。本研究检验了MNP涂层可减轻磁性牙科粘合剂美学影响这一假设。我们合成了具有二氧化硅涂层(MNPs-SiO)、钙基涂层(MNPs-Ca)和无涂层的FeO MNPs。使用透射电子显微镜(TEM)和扫描电子显微镜(SEM)研究了它们的形态。通过能量色散X射线光谱(EDX)评估了它们的化学成分,并使用振动样品磁强计测量了磁性。傅里叶变换红外光谱(FTIR)用于评估含MNP粘合剂的聚合情况。我们在磨牙模型上制备窝洞,将其分为四组(每组n = 15),使用相同的粘合剂和不同含量的MNP进行修复:第0组(G0)-无MNPs,G1-MNPs-SiO,G2-MNPs-Ca,G3-未涂层的MNPs。使用牙科分光光度计在CIELAB颜色空间中对修复体的颜色进行量化。MNPs-SiO呈球形,而MNPs-Ca具有立方形态。SiO层厚度为73.1 nm±9.9 nm;Ca(OH)层厚度为19.97 nm±2.27 nm。MNPs-SiO的饱和磁化强度为18.6 emu/g,MNPs-Ca为1.0 emu/g,未涂层的MNPs为65.7 emu/g。MNPs对粘合剂的光聚合有边际效应。G0和G2之间的平均色差接近50:50%的可接受阈值,而其他组与G0相差甚远。G2的平均白度指数与G0无显著差异;G1与G0略有偏差,而G3与G0有显著差异。这些结果表明,MNP涂层可减轻含MNP牙科粘合剂对修复体颜色的影响。
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