Salehi Amirmasoud, Asadollahfardi Gholamreza, Mafakheri Somaye, Homami Peyman, Akbardoost Javad, Soleymani Tushmanlo Hamid, Soleymani Tushmanlo Abolfazl
Kharazmi University, Karaj, Iran.
Iran University of Science & Technology, Tehran, Iran.
Sci Rep. 2025 Aug 9;15(1):29201. doi: 10.1038/s41598-025-13454-w.
Given the global water shortage crisis and the prevalent use of drinking water in concrete production, exploring practical solutions, such as reusing various wastewater, is essential. This study investigates the properties of self-compacting concrete (SCC) incorporating treated industrial wastewater sourced from dye factories. Propylene fibers at lengths of 6 mm and 12 mm were employed at volumes of 0.1% and 0.2%, with a water-to-cement ratio (w/c) of 0.5. Additionally, a 0.1% fiber concentration was tested in SCC with a w/c of 0.36, involving a 20% reduction in coarse aggregate in both scenarios except for control samples. While the use of treated industrial wastewater did not affect workability, propylene fibers reduced workability. When comparing samples using drinking water, the addition of 0.1% enhanced compressive strength by 10%, whereas a 0.2% propylene fiber concentration resulted in a 30% decrease in compressive strength. The inclusion of 1% propylene fibers with a length of 6 mm, combined with treated industrial wastewater, led to a reduction in compressive strength for low-cement mixes with a w/c of 0.5. Conversely, in high-cement mixes with a w/c of 0.36 using treated wastewater and 0.1% propylene fiber, the compressive strength increased compared to the control sample using treated industrial wastewater. Incorporating 2% silica fume as a cement replacement for both mixing designs resulted in a significant improvement in compressive strength at 90 days. Ultrasonic test results exhibited a strong correlation with compressive strength, highlighting the effectiveness of this method in evaluating mechanical properties. The volumetric water absorption increased with fiber incorporation, peaking at 66% higher than the control when using 0.2% fibers. However, the volumetric water absorption of the new sample mixture with 6 mm propylene fibers, 440 kg/m cement, treated industrial wastewater, and silica fume is under 5%. These findings underscore the potential of both propylene fibers and silica fume to enhance concrete strength and reduce volumetric water absorption when using treated industrial wastewater, indicating progress in sustainable concrete technologies. SEM images reveal that SCC samples made with treated industrial wastewater exhibit more voids, cracks, and Ettringite, potentially compromising their compressive strength. Nevertheless, the addition of silica fume improves the integration and homogeneity of the cement paste. Significantly, the presence of C-S-H is more prominent in these samples, with a lower Ca/Si ratio correlating with increased compressive strength.
鉴于全球水资源短缺危机以及饮用水在混凝土生产中的普遍使用,探索切实可行的解决方案,如回用各种废水,至关重要。本研究调查了掺入来自染料厂的处理后工业废水的自密实混凝土(SCC)的性能。使用长度为6毫米和12毫米的聚丙烯纤维,用量分别为0.1%和0.2%,水灰比(w/c)为0.5。此外,在水灰比为0.36的SCC中测试了0.1%的纤维浓度,除对照样品外,两种情况下粗骨料均减少20%。虽然使用处理后的工业废水不影响工作性,但聚丙烯纤维降低了工作性。与使用饮用水的样品相比,添加0.1%的聚丙烯纤维可使抗压强度提高10%,而纤维浓度为0.2%时,抗压强度降低30%。对于水灰比为0.5的低水泥混合料,掺入1%长度为6毫米的聚丙烯纤维并结合处理后的工业废水,会导致抗压强度降低。相反,在使用处理后的废水和0.1%聚丙烯纤维、水灰比为0.36的高水泥混合料中,与使用处理后的工业废水的对照样品相比,抗压强度有所提高。对于两种配合比设计,掺入2%的硅灰替代水泥,90天时抗压强度有显著提高。超声测试结果与抗压强度具有很强的相关性,突出了该方法在评估力学性能方面的有效性。体积吸水率随纤维掺入量增加而增加,当使用0.2%的纤维时,比对照样品高出66%达到峰值。然而,含有6毫米聚丙烯纤维、440千克/立方米水泥、处理后的工业废水和硅灰的新样品混合物的体积吸水率低于5%。这些发现强调了在使用处理后的工业废水时,聚丙烯纤维和硅灰在提高混凝土强度和降低体积吸水率方面的潜力,表明可持续混凝土技术取得了进展。扫描电子显微镜图像显示,用处理后的工业废水制成的SCC样品有更多孔隙、裂缝和钙矾石,可能会损害其抗压强度。然而,硅灰的添加改善了水泥浆体的结合和均匀性。值得注意的是,这些样品中C-S-H的存在更为显著,较低的钙硅比与抗压强度增加相关。