Silanization-Modified Lignin Nanoparticles for Paper Coating with Enhanced Liquid and Vapor Barriers, Frication Resistance, and Self-Cleaning Properties.

Paper's inherent hydrophilicity and porosity cause inadequate barrier properties, failing under high humidity/temperature. This study successfully developed a hydrophobic nanocoating agent (xLNPs-OTS) through silanization modification using D276 (lignin nanoparticles with a diameter of 276 nm) as the substrate and OTS (octadecyltrichlorosilane) as the functionalizing agent. By applying the coating to paper surfaces followed by a hot-pressing process, the paper achieved comprehensive performance enhancements, including superior water, oil, and vapor barrier properties, thermal stability, mechanical strength, frictional resistance, and self-cleaning capabilities. The Cobb 60 value of LOTSC3.5T120t30 (the coating made from the OTS silanized lignin with the coating amount of 3.5 g/m and a hot-pressing at 120 °C for 30 min) coated paper is as low as 3.75 g/m, and can withstand hot water at 100 °C for 60 min. The Cobb 60 value of the LOTSC20T120t30 (the coating made from the OTS silanized lignin with the coating amount of 20 g/m and a hot-pressing at 120 °C for 30 min) coated paper is reduced to 0.9 g/m, the Kit grade is 6, and all coated papers are endowed with self-cleaning features. This study advances lignin's high-value utilization, driving sustainable packaging and supporting eco-friendly paper material development.