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通过立体光刻增材制造用纳米材料增强剂提高牙科复合材料的性能。

Enhancing the performance of dental composites with nanomaterial reinforcements via stereolithographic additive manufacturing.

作者信息

Patadia Mitesh, Lappalainen Tripp T, Smith Riley, De Leon Ana, Downes Rebekah

机构信息

FAMU-FSU College of Engineering, 2525 Pottsdamer Rd, Tallahassee, FL, 32310, USA.

High-Performance Materials Institute (HPMI), 2005 Levy Avenue, Tallahassee, FL, 32310, USA.

出版信息

Discov Nano. 2025 Sep 2;20(1):149. doi: 10.1186/s11671-025-04337-0.

Abstract

AIM

This study investigates the enhancement of mechanical and morphological properties of dental resin composites through the incorporation of hexagonal boron nitride (hBN) and boron nitride nanotubes (BNNTs) using additive manufacturing techniques.

MATERIALS AND METHODS

hBN-modified resin (1 wt%) and BNNT-modified resin (0.1 wt%) were prepared separately, with BNNTs pre-dispersed in dimethylformamide (DMF) before mixing into the resin matrix. Stereolithography (SLA) 3D printing was employed to fabricate dental structures. Compression tests were conducted on neat resin, hBN-reinforced resin, and BNNT-reinforced resin, and scanning electron microscopy (SEM) was utilized to analyze fracture mechanisms. Finite element method (FEM) simulations further explored the interactions within the composites.

RESULTS

The compression strength of neat resin, hBN-reinforced resin, and BNNT-reinforced resin averaged 24.93 MPa, 25.92 MPa, and 36.31 MPa, respectively. SEM analysis revealed improved interfacial bonding, leading to enhanced load transfer and fracture resistance. FEM simulations corroborated these findings, highlighting the reinforcing effect of the nanomaterials.

摘要

目的

本研究通过使用增材制造技术加入六方氮化硼(hBN)和氮化硼纳米管(BNNTs)来研究牙科树脂复合材料的机械性能和形态性能的增强情况。

材料与方法

分别制备hBN改性树脂(1 wt%)和BNNT改性树脂(0.1 wt%),在将BNNTs混入树脂基体之前,先将其预分散在二甲基甲酰胺(DMF)中。采用立体光刻(SLA)3D打印技术制造牙科结构。对纯树脂、hBN增强树脂和BNNT增强树脂进行压缩试验,并利用扫描电子显微镜(SEM)分析断裂机制。有限元方法(FEM)模拟进一步探究了复合材料内部的相互作用。

结果

纯树脂、hBN增强树脂和BNNT增强树脂的压缩强度平均分别为24.93MPa、25.92MPa和36.31MPa。SEM分析显示界面结合得到改善,导致载荷传递增强和抗断裂性能提高。FEM模拟证实了这些发现,突出了纳米材料的增强效果。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dbf9/12401845/5f8c029370b3/11671_2025_4337_Fig4_HTML.jpg

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