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[天然水中痕量铬的活性炭预富集及其比色法测定]

[Preconcentration of trace chromium in natural water with activated carbon and its determination by colorimetry].

作者信息

Zhang K, Li C, Luo Y, He J, Luo X

出版信息

Hua Xi Yi Ke Da Xue Xue Bao. 1995 Jun;26(2):237-40.

PMID:7490040
Abstract

The adsorption and desorption behavior of chromium was studied. Trace chromium in water could be adsorbed on activated carbon at pH 9-10, then eluted with 0.5% sulfuric acid and determined by colorimetry. The content of chromium could be concentrated by 100 times. For sample, the coefficient of variation of 8 parallel determinations was 7.7%. The proposed method has been applied to the determination of trace chromium in natural waters with the recovery of 71.4%-90.0%, and with the detection limit of 0.04 microgram/L.

摘要

研究了铬的吸附和解吸行为。水中痕量铬在pH 9 - 10时可被活性炭吸附,然后用0.5%硫酸洗脱并比色测定。铬含量可浓缩100倍。对样品进行8次平行测定,变异系数为7.7%。该方法已应用于天然水中痕量铬的测定,回收率为71.4% - 90.0%,检测限为0.04微克/升。

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