Tahvonen R, Kumpulainen J
Laboratory of Food Chemistry, Agricultural Research Centre of Finland, Jokioinen.
Food Addit Contam. 1995 Mar-Apr;12(2):263-79. doi: 10.1080/02652039509374301.
In order to determine the present contribution of vegetables and berries to the intake of lead and cadmium in Finland major vegetable groups as well as strawberries and blackcurrants were collected from wholesale distribution centres, orchards and the food industry. Pooled samples were mixed to represent wholesale distribution centres, exporting countries or geographical regions. Lead and cadmium were determined after wet digestion in concentrated HNO3 using ETAAS with Zeeman effect background correction and 0.1% palladium for lead and (NH4)H2PO4 for cadmium matrix modification. The method of standard additions was used for the quantification. The mean lead and cadmium contents found were: iceberg lettuce 1.1 and 20.9, butterhead lettuce 4.5 and 12.2, Chinese cabbage 1.4 and 11.1, cauliflower 1.6 and 7.1, cucumber 0.7 and 0.6, carrot 5.9 and 24.6, tomato 1.5 and 1.5, leek 3.8 and 12.8, cabbage 1.3 and 3.1, paprika 3.1 and 5.3, potato 5 and 6 (domestic) or 5 and 31 (imported), strawberry 6.5 and 13.7, blackcurrant 12.7 and 1.4 micrograms/kg. The contents found in this study are the lowest reported so far in Finland and equal to or lower than those found elsewhere.
为了确定芬兰蔬菜和浆果对铅和镉摄入量的当前贡献,从批发配送中心、果园和食品工业收集了主要蔬菜种类以及草莓和黑加仑。将混合样本混合以代表批发配送中心、出口国或地理区域。采用湿法消解,在浓硝酸中消解后,使用带塞曼效应背景校正的石墨炉原子吸收光谱法(ETAAS)测定铅和镉,铅的基体改进剂为0.1%钯,镉的基体改进剂为磷酸二氢铵(NH4)H2PO4。采用标准加入法进行定量。所测得的铅和镉平均含量如下:生菜1.1和20.9、奶油生菜4.5和12.2、大白菜1.4和11.1、花椰菜1.6和7.1、黄瓜0.7和0.6、胡萝卜5.9和24.6、番茄1.5和1.5、韭菜3.8和12.8、卷心菜1.3和3.1、甜椒3.1和5.3、土豆5和6(国内)或5和31(进口)、草莓6.5和13.7、黑加仑12.7和1.4微克/千克。本研究中发现的含量是芬兰迄今报告的最低值,与其他地方发现的含量相当或更低。