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μ-氧代双[(5,10,15,20-四苯基卟啉基)氧钼(V)]

mu-Oxo-bis[(5,10,15,20-tetraphenylporphyrinato)oxomolybdenum(V)].

作者信息

Cheng B, Scheidt W R

机构信息

Department of Chemistry and Biochemistry, University of Notre Dame, IN 46556, USA.

出版信息

Acta Crystallogr C. 1996 Apr 15;52 ( Pt 4):832-5. doi: 10.1107/s0108270195014648.

Abstract

The crystal structure of a new solvated crystal form of the title complex, [¿Mo(O)(TPP)¿2O].1.5H2O.0.5CH2Cl2 (TPP = C44H28N4), has been determined. The dimeric molecule is in a general position, and the overall structural features are extremely similar to those of the previously reported non-solvated form.

摘要

已确定标题配合物[¿Mo(O)(TPP)¿2O].1.5H2O.0.5CH2Cl2(TPP = C44H28N4)的一种新的溶剂化晶体形式的晶体结构。二聚体分子处于一般位置,其整体结构特征与先前报道的非溶剂化形式极为相似。

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