Kinumaki A, Harada K, Furumai T, Suzuki M
J Antibiot (Tokyo). 1976 Nov;29(11):1209-17. doi: 10.7164/antibiotics.29.1209.
Mass spectra of platenolides--biosynthetic precursors of the 16-membered macrolide antibiotics, platenomycins--and their derivatives are discussed in detail especially in connection with structure elucidation. Mass spectrometry was of great use in establishing the structures for platenolides I (1) and II (2).
详细讨论了扁平内酯类化合物(16元大环内酯类抗生素扁平霉素的生物合成前体)及其衍生物的质谱,尤其是在结构解析方面。质谱在确定扁平内酯I(1)和II(2)的结构中发挥了重要作用。