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[球状蛋白质之间的电子转移。一个矩阵元素的评估]

[Electron transfer between globular proteins. Evaluation of a matrix element].

作者信息

Lakhno V D, Chuev G N, Ustinin M N

机构信息

Institute of Mathematical Problems of Biology, Russian Academy of Sciences, Pushchino, Moscow Region, Russia.

出版信息

Biofizika. 1998 Nov-Dec;43(6):949-52.

Abstract

The dependence of the matrix element of the probability of interprotein electron transfer on the mutual orientation of the donor and acceptor centers and the distance between them was calculated. The calculations were made under the assumption that electron transfer proceeds mainly by a collective excitation of polaron nature, like a solvated electron state. The results obtained are consistent with experimental data and indicate the nonexponential behavior of this dependence in the case when the distance transfer is less than 20 A.

摘要

计算了蛋白质间电子转移概率的矩阵元对供体和受体中心的相互取向及其之间距离的依赖性。计算是在电子转移主要通过极化子性质的集体激发进行的假设下进行的,就像溶剂化电子态一样。所得结果与实验数据一致,并表明在转移距离小于20埃的情况下,这种依赖性呈现非指数行为。

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