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Alteration of O,O-dimethyl S-[alpha-(carboethoxy)benzyl] phosphorodithioate (phenthoate) in citrus, water, and upon exposure to air and sunlight.

作者信息

Takade D Y, Seo M S, Kao T S, Fukuto T R

出版信息

Arch Environ Contam Toxicol. 1976;5(1):63-86. doi: 10.1007/BF02220891.

DOI:10.1007/BF02220891
PMID:1015864
Abstract

The fate of 32P- and 14C-labeled O,O-dimethyl S-[alpha-(carboethoxy)benzyl] phosphorodithioate (phenthoate) was determined in citrus, water, and upon exposure to air and sunlight. The products recovered from citrus and glass plates exposed to sunlight were unchanged phenthoate, phenthoate oxon, demethyl phenthoate, mandelic acid, bis-[alpha-(carboethoxy)benzyl] disulfide, O,O-dimethyl phosphorothioic and phosphorodithioic acid. Similar products generally were found in citrus leaf and fruit extracts. Phenthoate was fairly stable in phosphate buffered water with a half-life of approximately 12 days at pH 8.0. The major hydrolysis products were phenthoate acid, demethyl phenthoate and demethyl phenthoate oxon.

摘要

相似文献

1
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引用本文的文献

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2
3. Metabolism of pesticides. The nonmetabolic decomposition of pesticides.
Ann N Y Acad Sci. 1969;160(1):82-96. doi: 10.1111/j.1749-6632.1969.tb15829.x.
3
The metabolism of O-(4-bromo-2, 5-dichlorophenyl) O-methyl phenylphosphonothioate (leptophos) in white mice and on cotton plants.
Arch Environ Contam Toxicol. 1973 Jul;1(2):133-47. doi: 10.1007/BF01986003.