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[三种墨角藻科糖基甘油二酯的硫酸酯、磺酸酯和磷酸酯的结构、含量及组成]

[Structure, amount and composition of sulfuric, sulfonic and phosphoric esters of glycosyldiglycerides of three fucacea].

作者信息

Liem P Q, Laur M H

出版信息

Biochimie. 1976;58(11-12):1367-80.

PMID:1016655
Abstract

The mono and polyester glycosyl sulfates or phosphate diglycerides account for a group of polar lipids which is found in large amounts in the three fucacae that are studied: Pelvetia canaliculata (L) Deen and Thur, Fucus vesiculosus (L), Fucus serratus (L). These polar lipids have been shown to have complex structures, most of them are unknown in the present nomenclature. Both quantity and composition of these polar lipids are species characteristics, forming the equipment of polar lipids for every species of algae. Glycosyl ester sulfate and phosphate diglycerides are very unstable substances when pure, moreover photolabile and thremodegradable. This extreme fragility caused many difficulties in the determination of molecular structures which require a very high purity of isolated substances, The determination of the structures, studies of quantities and composition cytological localization of these polar lipids should allow to define clearly their physiological function and importance from the biochemical and ecological point of view.

摘要

单糖基硫酸酯和聚酯硫酸酯或磷酸甘油二酯属于一类极性脂质,在研究的三种墨角藻中含量丰富,即:鹿角菜(Pelvetia canaliculata (L) Deen and Thur)、泡叶藻(Fucus vesiculosus (L))、锯齿墨角藻(Fucus serratus (L))。这些极性脂质具有复杂的结构,在目前的命名法中,大多数都是未知的。这些极性脂质的数量和组成都是物种特征,构成了每种藻类的极性脂质组成。硫酸糖基酯和磷酸甘油二酯在纯净时是非常不稳定的物质,而且对光和热都不稳定。这种极端的脆弱性给分子结构的测定带来了许多困难,因为测定需要分离出非常高纯度的物质。对这些极性脂质的结构测定、数量和组成研究以及细胞学定位,应该能够从生化和生态角度清楚地界定它们的生理功能和重要性。

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