Toth RA
California Institute of Technology, Jet Propulsion Laboratory, Pasadena, California, 91109
J Mol Spectrosc. 1999 May;195(1):98-122. doi: 10.1006/jmsp.1999.7815.
Measurements of line positions and absolute strengths of D2O from 700 to 3100 cm-1 were obtained with a Fourier transform spectrometer. The data were analyzed to obtain energy levels of the (000), (010), (020), (100), and (001) vibrational states of D216O and, first time assignments of the (010)-(000) band of D217O, including the energy levels of the (000) and (010) states. The measurements included transitions of the (010)-(000) band of D218O; however, observations from a previous study provided adequate information for the energy levels. The measured linestrengths of the (010)-(000) bands of D216O, D217O, and D218O were fitted to the model, which included up to 19 dipole-moment expansion coefficients. The observed linestrengths of the D216O interacting bands, (020)-(010), (100)-(010), and (001)-(010), were analyzed using a full perturbation treatment. Copyright 1999 Academic Press.
使用傅里叶变换光谱仪获得了重水(D2O)在700至3100厘米-1范围内的谱线位置和绝对强度测量值。对数据进行分析以获得D216O的(000)、(010)、(020)、(100)和(001)振动态的能级,以及首次对D217O的(010)-(000)带进行归属,包括(000)和(010)态的能级。测量包括D218O的(010)-(000)带的跃迁;然而,先前一项研究的观测结果为能级提供了足够的信息。将D216O、D217O和D218O的(010)-(000)带的测量谱线强度拟合到该模型,该模型包括多达19个偶极矩展开系数。使用全微扰处理分析了D216O相互作用带(020)-(010)、(100)-(010)和(001)-(010)的观测谱线强度。版权所有1999年学术出版社。