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差分脉冲阳极溶出伏安法作为重金属中毒的快速筛查技术。

Differential pulse anodic stripping voltammetry as a rapid screening technique for heavy metal intoxications.

作者信息

Franke J P, de Zeeuw R A

出版信息

Arch Toxicol. 1976 Dec 23;37(1):47-55. doi: 10.1007/BF00353354.

DOI:10.1007/BF00353354
PMID:1036907
Abstract

This paper describes a relatively simple and rapid analytical procedure capable to carry out systematic screening for 10 heavy metals, namely mercury, bismuth, antimony, copper, lead, tin, thallium, indium, cadmium and zinc. Differential pulse anodic stripping voltammetry was chosen because of its simplicity, speed, low cost, low detection limits, screening potential for a wide selection of metals and the combined qualitative and quantitative output. The method of identification is based on measuring peak potentials in 2 different types of electrolyte solution, using 2 different electrodes. Complexing agents are used to mask certain elements.

摘要

本文描述了一种相对简单且快速的分析程序,能够对10种重金属进行系统筛查,这10种重金属分别是汞、铋、锑、铜、铅、锡、铊、铟、镉和锌。之所以选择差分脉冲阳极溶出伏安法,是因为其具有操作简单、速度快、成本低、检测限低、可对多种金属进行筛查以及兼具定性和定量输出等特点。识别方法基于在两种不同类型的电解质溶液中使用两种不同电极测量峰值电位。使用络合剂来掩蔽某些元素。

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Arch Toxicol. 1976 Dec 23;37(1):47-55. doi: 10.1007/BF00353354.
2
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Simultaneous determination of Zn, Cd, Pb, and Cu in urine of patients with blackfoot disease using anodic stripping voltammetry.
Biol Trace Elem Res. 1993 Sep;38(3):233-41. doi: 10.1007/BF02785308.
2
Biomonitoring lead exposure with delta-aminolevulinate dehydratase (ALA-D) activity ratios.通过δ-氨基乙酰丙酸脱水酶(ALA-D)活性比率进行生物监测铅暴露。
Int Arch Occup Environ Health. 1982;51(1):15-24. doi: 10.1007/BF00378406.

本文引用的文献

1
A rapid and specific method for the determination of traces of thallium directly in urine by differential pulse anodic stripping voltammetry.
Arch Toxicol. 1975 Oct 20;34(2):137-43. doi: 10.1007/BF00353314.
2
[Contribution to the determination of thallium in human head hair in forensic cases with flameless atomic absorption spectrometry].
Arch Toxicol. 1975 Sep 5;34(1):17-26. doi: 10.1007/BF00353335.