Castellari C, Feroci G, Ottani S
Dipartimento di Chimica G. Ciamician, Universitá di Bologna, Italy.
Acta Crystallogr C. 1999 Jun 15;55 ( Pt 6):907-10. doi: 10.1107/s0108270199002206.
The structure of the centrosymmetric dimeric copper(II) title compound, [Cu2(C14H10Cl2NO2)4(C3H6O)2] C2H4O, has been determined and compared with the structures of analogous O-bridged CuII dimers. Polarographic experiments on aqueous solutions containing a mixture of the CuII ion and diclofenac have been used to determine both the formation constant [1 (1) x 10(8)] and the solubility product [2 (1) x 10(-12)] of the complex.