Hinderling C, Chen P
Laboratorium für Organische Chemie, Eidgenössische Technische Hochschule, Universitätstrasse 16, CH-8092 Zürich (Switzerland).
Angew Chem Int Ed Engl. 1999 Aug;38(15):2253-2256.
The simultaneous screening of catalysts according to their propensity for catalyzing the polymerization of ethylene (see scheme) can be achieved with the help of electrospray ionization tandem mass spectrometry. A small (eight catalysts) library of Pd(II) complexes synthesized simultaneously in a one-pot reaction has demonstrated the efficiency of this new screening technique. This method could be widened to libraries of other olefin polymerization catalysts.
借助电喷雾电离串联质谱法，可以根据催化剂催化乙烯聚合的倾向（见方案）同时筛选催化剂。在一锅反应中同时合成的一个小型（八种催化剂）钯（II）配合物文库已经证明了这种新筛选技术的有效性。该方法可以扩展到其他烯烃聚合催化剂的文库。
